Characterization of nanoporous materials prepared from montmorillonite clay and its application to the decolorization of mare's milk oil View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-01

AUTHORS

J. Temuujin, M. Senna, Ts. Jadambaa, D. Burmaa, Sh. Erdenechimeg, J. Amarsanaa, G. Burmaa

ABSTRACT

Nanoporous materials have been prepared by leaching the purified montmorillonite clay with sulfuric acid (H2SO4) solution with varying concentrations (0.5–2 M) at 80°C for 0.5–4 h. Acid leaching causes partial amorphisation of the clay with depletion of MgO, Al2O3, CaO and Fe2O3 components mostly from interlayer and octahedral sites. This increases the specific surface area by more than 3 times, i.e. from 49.1 to 157 m2/g. The pore-size distribution curves calculated from the adsorption isotherms of the leached montmorillonite show that most of the pores are in the mesoporous region with their diameter ranging 3–4 nm. This material turns out to be appropriate for bleaching of the mare's milk oil. The chemical and structural changes of the acid-leached montmorillonite are discussed in terms of the decolorization capacity. More... »

PAGES

49-53

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10934-006-5489-z

DOI

http://dx.doi.org/10.1007/s10934-006-5489-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010475684


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, 223-8522, Yokohama, Japan", 
          "id": "http://www.grid.ac/institutes/grid.26091.3c", 
          "name": [
            "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, 223-8522, Yokohama, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Temuujin", 
        "givenName": "J.", 
        "id": "sg:person.016275474025.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016275474025.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, 223-8522, Yokohama, Japan", 
          "id": "http://www.grid.ac/institutes/grid.26091.3c", 
          "name": [
            "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, 223-8522, Yokohama, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Senna", 
        "givenName": "M.", 
        "id": "sg:person.011363404413.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363404413.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia", 
          "id": "http://www.grid.ac/institutes/grid.440461.3", 
          "name": [
            "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jadambaa", 
        "givenName": "Ts.", 
        "id": "sg:person.012176101261.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012176101261.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia", 
          "id": "http://www.grid.ac/institutes/grid.440461.3", 
          "name": [
            "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Burmaa", 
        "givenName": "D.", 
        "id": "sg:person.013325137513.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013325137513.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia", 
          "id": "http://www.grid.ac/institutes/grid.440461.3", 
          "name": [
            "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Erdenechimeg", 
        "givenName": "Sh.", 
        "id": "sg:person.015515461113.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015515461113.80"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia", 
          "id": "http://www.grid.ac/institutes/grid.440461.3", 
          "name": [
            "New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Amarsanaa", 
        "givenName": "J.", 
        "id": "sg:person.010405350713.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010405350713.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar 51, Mongolia", 
          "id": "http://www.grid.ac/institutes/grid.425925.d", 
          "name": [
            "Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar 51, Mongolia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Burmaa", 
        "givenName": "G.", 
        "id": "sg:person.012511300417.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012511300417.24"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1346/ccmn.2003.0510309", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033386441", 
          "https://doi.org/10.1346/ccmn.2003.0510309"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02541394", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008091455", 
          "https://doi.org/10.1007/bf02541394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02653285", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005953108", 
          "https://doi.org/10.1007/bf02653285"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-01", 
    "datePublishedReg": "2006-01-01", 
    "description": "Nanoporous materials have been prepared by leaching the purified montmorillonite clay with sulfuric acid (H2SO4) solution with varying concentrations (0.5\u20132 M) at 80\u00b0C for 0.5\u20134 h. Acid leaching causes partial amorphisation of the clay with depletion of MgO, Al2O3, CaO and Fe2O3 components mostly from interlayer and octahedral sites. This increases the specific surface area by more than 3 times, i.e. from 49.1 to 157 m2/g. The pore-size distribution curves calculated from the adsorption isotherms of the leached montmorillonite show that most of the pores are in the mesoporous region with their diameter ranging 3\u20134 nm. This material turns out to be appropriate for bleaching of the mare's milk oil. The chemical and structural changes of the acid-leached montmorillonite are discussed in terms of the decolorization capacity.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10934-006-5489-z", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136407", 
        "issn": [
          "1380-2224", 
          "1573-4854"
        ], 
        "name": "Journal of Porous Materials", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "13"
      }
    ], 
    "keywords": [
      "nanoporous materials", 
      "montmorillonite clay", 
      "specific surface area", 
      "sulfuric acid solution", 
      "adsorption isotherms", 
      "mesoporous region", 
      "pore size distribution curves", 
      "m2/", 
      "Fe2O3 component", 
      "acid solution", 
      "surface area", 
      "octahedral sites", 
      "depletion of MgO", 
      "decolorization capacity", 
      "acid leaching", 
      "partial amorphisation", 
      "structural changes", 
      "materials", 
      "clay", 
      "decolorization", 
      "montmorillonite", 
      "isotherms", 
      "oil", 
      "distribution curves", 
      "Al2O3", 
      "interlayer", 
      "pores", 
      "leaching", 
      "characterization", 
      "amorphisation", 
      "MgO", 
      "CaO", 
      "solution", 
      "bleaching", 
      "concentration", 
      "diameter", 
      "applications", 
      "capacity", 
      "sites", 
      "curves", 
      "components", 
      "time", 
      "terms", 
      "area", 
      "region", 
      "changes", 
      "depletion"
    ], 
    "name": "Characterization of nanoporous materials prepared from montmorillonite clay and its application to the decolorization of mare's milk oil", 
    "pagination": "49-53", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1010475684"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10934-006-5489-z"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10934-006-5489-z", 
      "https://app.dimensions.ai/details/publication/pub.1010475684"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T16:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_420.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10934-006-5489-z"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10934-006-5489-z'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10934-006-5489-z'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10934-006-5489-z'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10934-006-5489-z'


 

This table displays all metadata directly associated to this object as RDF triples.

172 TRIPLES      21 PREDICATES      77 URIs      64 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10934-006-5489-z schema:about anzsrc-for:03
2 anzsrc-for:0306
3 anzsrc-for:09
4 anzsrc-for:0912
5 schema:author N023664ee42a94426a00e3c04678237f8
6 schema:citation sg:pub.10.1007/bf02541394
7 sg:pub.10.1007/bf02653285
8 sg:pub.10.1346/ccmn.2003.0510309
9 schema:datePublished 2006-01
10 schema:datePublishedReg 2006-01-01
11 schema:description Nanoporous materials have been prepared by leaching the purified montmorillonite clay with sulfuric acid (H2SO4) solution with varying concentrations (0.5–2 M) at 80°C for 0.5–4 h. Acid leaching causes partial amorphisation of the clay with depletion of MgO, Al2O3, CaO and Fe2O3 components mostly from interlayer and octahedral sites. This increases the specific surface area by more than 3 times, i.e. from 49.1 to 157 m2/g. The pore-size distribution curves calculated from the adsorption isotherms of the leached montmorillonite show that most of the pores are in the mesoporous region with their diameter ranging 3–4 nm. This material turns out to be appropriate for bleaching of the mare's milk oil. The chemical and structural changes of the acid-leached montmorillonite are discussed in terms of the decolorization capacity.
12 schema:genre article
13 schema:isAccessibleForFree false
14 schema:isPartOf Nc294f6d5e9da49628680863a5768bde1
15 Nc334ede03e8043e1ae717a8f3e218d17
16 sg:journal.1136407
17 schema:keywords Al2O3
18 CaO
19 Fe2O3 component
20 MgO
21 acid leaching
22 acid solution
23 adsorption isotherms
24 amorphisation
25 applications
26 area
27 bleaching
28 capacity
29 changes
30 characterization
31 clay
32 components
33 concentration
34 curves
35 decolorization
36 decolorization capacity
37 depletion
38 depletion of MgO
39 diameter
40 distribution curves
41 interlayer
42 isotherms
43 leaching
44 m2/
45 materials
46 mesoporous region
47 montmorillonite
48 montmorillonite clay
49 nanoporous materials
50 octahedral sites
51 oil
52 partial amorphisation
53 pore size distribution curves
54 pores
55 region
56 sites
57 solution
58 specific surface area
59 structural changes
60 sulfuric acid solution
61 surface area
62 terms
63 time
64 schema:name Characterization of nanoporous materials prepared from montmorillonite clay and its application to the decolorization of mare's milk oil
65 schema:pagination 49-53
66 schema:productId N6f03cdf6e0d8483b9f3d91e9e5efc637
67 Ncf5334e73d5a4d2abe92936b80a4f9d4
68 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010475684
69 https://doi.org/10.1007/s10934-006-5489-z
70 schema:sdDatePublished 2022-08-04T16:55
71 schema:sdLicense https://scigraph.springernature.com/explorer/license/
72 schema:sdPublisher Nd4a89f0c7cec4f48a06978cf29908ea1
73 schema:url https://doi.org/10.1007/s10934-006-5489-z
74 sgo:license sg:explorer/license/
75 sgo:sdDataset articles
76 rdf:type schema:ScholarlyArticle
77 N023664ee42a94426a00e3c04678237f8 rdf:first sg:person.016275474025.53
78 rdf:rest Nf28b272a048a4ed08b8343c1e7864564
79 N55a7aab6effb4790a97c5476236aeee8 rdf:first sg:person.015515461113.80
80 rdf:rest N681a864c56de4b36ae2a7583fd01c94a
81 N681a864c56de4b36ae2a7583fd01c94a rdf:first sg:person.010405350713.37
82 rdf:rest N95cc8736c0724b78ad6531a52e724123
83 N6f03cdf6e0d8483b9f3d91e9e5efc637 schema:name doi
84 schema:value 10.1007/s10934-006-5489-z
85 rdf:type schema:PropertyValue
86 N77943a2513924be7addd57f4058ab008 rdf:first sg:person.013325137513.02
87 rdf:rest N55a7aab6effb4790a97c5476236aeee8
88 N95cc8736c0724b78ad6531a52e724123 rdf:first sg:person.012511300417.24
89 rdf:rest rdf:nil
90 Nc294f6d5e9da49628680863a5768bde1 schema:issueNumber 1
91 rdf:type schema:PublicationIssue
92 Nc334ede03e8043e1ae717a8f3e218d17 schema:volumeNumber 13
93 rdf:type schema:PublicationVolume
94 Ncf5334e73d5a4d2abe92936b80a4f9d4 schema:name dimensions_id
95 schema:value pub.1010475684
96 rdf:type schema:PropertyValue
97 Nd4a89f0c7cec4f48a06978cf29908ea1 schema:name Springer Nature - SN SciGraph project
98 rdf:type schema:Organization
99 Ne15bcb4ea21543298ee013a76917fd5a rdf:first sg:person.012176101261.10
100 rdf:rest N77943a2513924be7addd57f4058ab008
101 Nf28b272a048a4ed08b8343c1e7864564 rdf:first sg:person.011363404413.06
102 rdf:rest Ne15bcb4ea21543298ee013a76917fd5a
103 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
104 schema:name Chemical Sciences
105 rdf:type schema:DefinedTerm
106 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
107 schema:name Physical Chemistry (incl. Structural)
108 rdf:type schema:DefinedTerm
109 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
110 schema:name Engineering
111 rdf:type schema:DefinedTerm
112 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
113 schema:name Materials Engineering
114 rdf:type schema:DefinedTerm
115 sg:journal.1136407 schema:issn 1380-2224
116 1573-4854
117 schema:name Journal of Porous Materials
118 schema:publisher Springer Nature
119 rdf:type schema:Periodical
120 sg:person.010405350713.37 schema:affiliation grid-institutes:grid.440461.3
121 schema:familyName Amarsanaa
122 schema:givenName J.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010405350713.37
124 rdf:type schema:Person
125 sg:person.011363404413.06 schema:affiliation grid-institutes:grid.26091.3c
126 schema:familyName Senna
127 schema:givenName M.
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363404413.06
129 rdf:type schema:Person
130 sg:person.012176101261.10 schema:affiliation grid-institutes:grid.440461.3
131 schema:familyName Jadambaa
132 schema:givenName Ts.
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012176101261.10
134 rdf:type schema:Person
135 sg:person.012511300417.24 schema:affiliation grid-institutes:grid.425925.d
136 schema:familyName Burmaa
137 schema:givenName G.
138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012511300417.24
139 rdf:type schema:Person
140 sg:person.013325137513.02 schema:affiliation grid-institutes:grid.440461.3
141 schema:familyName Burmaa
142 schema:givenName D.
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013325137513.02
144 rdf:type schema:Person
145 sg:person.015515461113.80 schema:affiliation grid-institutes:grid.440461.3
146 schema:familyName Erdenechimeg
147 schema:givenName Sh.
148 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015515461113.80
149 rdf:type schema:Person
150 sg:person.016275474025.53 schema:affiliation grid-institutes:grid.26091.3c
151 schema:familyName Temuujin
152 schema:givenName J.
153 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016275474025.53
154 rdf:type schema:Person
155 sg:pub.10.1007/bf02541394 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008091455
156 https://doi.org/10.1007/bf02541394
157 rdf:type schema:CreativeWork
158 sg:pub.10.1007/bf02653285 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005953108
159 https://doi.org/10.1007/bf02653285
160 rdf:type schema:CreativeWork
161 sg:pub.10.1346/ccmn.2003.0510309 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033386441
162 https://doi.org/10.1346/ccmn.2003.0510309
163 rdf:type schema:CreativeWork
164 grid-institutes:grid.26091.3c schema:alternateName Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, 223-8522, Yokohama, Japan
165 schema:name Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, 223-8522, Yokohama, Japan
166 rdf:type schema:Organization
167 grid-institutes:grid.425925.d schema:alternateName Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar 51, Mongolia
168 schema:name Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar 51, Mongolia
169 rdf:type schema:Organization
170 grid-institutes:grid.440461.3 schema:alternateName New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia
171 schema:name New Materials Center, Mongolian University of Science and Technology, Ulaanbaatar 46, Mongolia
172 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...