Modification of Novel Chitosan-Starch Cross-Linked Derivatives Polymers: Synthesis and Characterization View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-05

AUTHORS

Ernestine Atangana, Trevor T. Chiweshe, Hester Roberts

ABSTRACT

This paper reports on the synthesis and characterization of cross-linked chitosan products prepared from using crab, shrimp beads and ten different cross-linked polymers which includes; glutaraldehyde, formaldehyde, epichlorohydrine, maleic anhydride, p-benzoquinone, poly (ethylene) glycol diglycidyl ether (PEG diglycidyl ether), 1-vinyl-2-pyrrolidone, 1,3-dichloroaceone, acrylic acid and s-methyl-benzylamine. Characterization of the cross-liked chitosan products was done using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) to determine the structural morphology and the stretching frequencies of the products. The obtained FTIR stretching frequencies of the cross-linked chitosan products were matched against the starting material and the literature values to confirm the products. SEM analysis showed mixtures of regular and amorphous products. Different percentage yields (crab, 26–98% and shrimp, 30–88%) were obtained for the cross-linked chitosan products depending on the cross-linked polymer used. More... »

PAGES

1-17

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10924-019-01407-0

DOI

http://dx.doi.org/10.1007/s10924-019-01407-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112361538


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Central University of Technology", 
          "id": "https://www.grid.ac/institutes/grid.428369.2", 
          "name": [
            "Department of life sciences, Central University of Technology, Free State, Bloemfontein, South Africa"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Atangana", 
        "givenName": "Ernestine", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institution for Groundwater Studies, University of the Free Sate, Bloemfontein, South Africa"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chiweshe", 
        "givenName": "Trevor T.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Central University of Technology", 
          "id": "https://www.grid.ac/institutes/grid.428369.2", 
          "name": [
            "Department of life sciences, Central University of Technology, Free State, Bloemfontein, South Africa"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Roberts", 
        "givenName": "Hester", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.jtemb.2005.02.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000135360"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jtemb.2005.02.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000135360"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.4314/wsa.v27i1.5002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006921417"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.4314/wsa.v27i1.5002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006921417"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0032-3861(00)00402-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009257327"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.60.444", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022311269"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.progpolymsci.2006.06.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026434192"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1381-5148(01)00113-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033770415"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.1974.070180815", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038337825"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.scitotenv.2004.01.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039723277"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/15226510801913918", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041735451"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.seppur.2004.08.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049778032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ijbiomac.2011.11.026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049906271"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.progpolymsci.2004.11.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051666301"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/i300013a033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055529309"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ie060514s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055600089"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ie060514s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055600089"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ie9701579", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055646421"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ie9701579", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055646421"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-05", 
    "datePublishedReg": "2019-05-01", 
    "description": "This paper reports on the synthesis and characterization of cross-linked chitosan products prepared from using crab, shrimp beads and ten different cross-linked polymers which includes; glutaraldehyde, formaldehyde, epichlorohydrine, maleic anhydride, p-benzoquinone, poly (ethylene) glycol diglycidyl ether (PEG diglycidyl ether), 1-vinyl-2-pyrrolidone, 1,3-dichloroaceone, acrylic acid and s-methyl-benzylamine. Characterization of the cross-liked chitosan products was done using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) to determine the structural morphology and the stretching frequencies of the products. The obtained FTIR stretching frequencies of the cross-linked chitosan products were matched against the starting material and the literature values to confirm the products. SEM analysis showed mixtures of regular and amorphous products. Different percentage yields (crab, 26\u201398% and shrimp, 30\u201388%) were obtained for the cross-linked chitosan products depending on the cross-linked polymer used.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10924-019-01407-0", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1297558", 
        "issn": [
          "1064-7546", 
          "1572-8919"
        ], 
        "name": "Journal of Polymers and the Environment", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "27"
      }
    ], 
    "name": "Modification of Novel Chitosan-Starch Cross-Linked Derivatives Polymers: Synthesis and Characterization", 
    "pagination": "1-17", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "9ffc1465d70ef1ee32ba6ee1171785fe44f34065c4ba55d5d4e479c5f799623c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10924-019-01407-0"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112361538"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10924-019-01407-0", 
      "https://app.dimensions.ai/details/publication/pub.1112361538"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000371_0000000371/records_130794_00000006.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs10924-019-01407-0"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10924-019-01407-0'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10924-019-01407-0'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10924-019-01407-0'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10924-019-01407-0'


 

This table displays all metadata directly associated to this object as RDF triples.

119 TRIPLES      21 PREDICATES      42 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10924-019-01407-0 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N5279182041d746799b499705645fcf41
4 schema:citation https://doi.org/10.1002/app.1974.070180815
5 https://doi.org/10.1016/j.ijbiomac.2011.11.026
6 https://doi.org/10.1016/j.jtemb.2005.02.010
7 https://doi.org/10.1016/j.progpolymsci.2004.11.002
8 https://doi.org/10.1016/j.progpolymsci.2006.06.001
9 https://doi.org/10.1016/j.scitotenv.2004.01.002
10 https://doi.org/10.1016/j.seppur.2004.08.002
11 https://doi.org/10.1016/s0032-3861(00)00402-x
12 https://doi.org/10.1016/s1381-5148(01)00113-4
13 https://doi.org/10.1021/i300013a033
14 https://doi.org/10.1021/ie060514s
15 https://doi.org/10.1021/ie9701579
16 https://doi.org/10.1080/15226510801913918
17 https://doi.org/10.1246/bcsj.60.444
18 https://doi.org/10.4314/wsa.v27i1.5002
19 schema:datePublished 2019-05
20 schema:datePublishedReg 2019-05-01
21 schema:description This paper reports on the synthesis and characterization of cross-linked chitosan products prepared from using crab, shrimp beads and ten different cross-linked polymers which includes; glutaraldehyde, formaldehyde, epichlorohydrine, maleic anhydride, p-benzoquinone, poly (ethylene) glycol diglycidyl ether (PEG diglycidyl ether), 1-vinyl-2-pyrrolidone, 1,3-dichloroaceone, acrylic acid and s-methyl-benzylamine. Characterization of the cross-liked chitosan products was done using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) to determine the structural morphology and the stretching frequencies of the products. The obtained FTIR stretching frequencies of the cross-linked chitosan products were matched against the starting material and the literature values to confirm the products. SEM analysis showed mixtures of regular and amorphous products. Different percentage yields (crab, 26–98% and shrimp, 30–88%) were obtained for the cross-linked chitosan products depending on the cross-linked polymer used.
22 schema:genre research_article
23 schema:inLanguage en
24 schema:isAccessibleForFree false
25 schema:isPartOf N229ef99b2e394e3fb496b8731e49156c
26 N6f2cdcb230384086a329f233d955091c
27 sg:journal.1297558
28 schema:name Modification of Novel Chitosan-Starch Cross-Linked Derivatives Polymers: Synthesis and Characterization
29 schema:pagination 1-17
30 schema:productId N36804ca7eec647e481a6c0743e363a50
31 N5baeedb05a0e4f96ba336fac841ee0bc
32 N5dc20ff5cffa41b3a3b016bc086ca974
33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112361538
34 https://doi.org/10.1007/s10924-019-01407-0
35 schema:sdDatePublished 2019-04-11T13:50
36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
37 schema:sdPublisher N97ca3833bf4843dd8b6bcb54a0b86549
38 schema:url https://link.springer.com/10.1007%2Fs10924-019-01407-0
39 sgo:license sg:explorer/license/
40 sgo:sdDataset articles
41 rdf:type schema:ScholarlyArticle
42 N07e9204469bc49cbb11238c76dccab9f rdf:first N796b64f0e27a490bb2475e75ba89fc45
43 rdf:rest rdf:nil
44 N19eb47b008034b7a8af98894b35e6d5f schema:affiliation https://www.grid.ac/institutes/grid.428369.2
45 schema:familyName Atangana
46 schema:givenName Ernestine
47 rdf:type schema:Person
48 N229ef99b2e394e3fb496b8731e49156c schema:volumeNumber 27
49 rdf:type schema:PublicationVolume
50 N36804ca7eec647e481a6c0743e363a50 schema:name dimensions_id
51 schema:value pub.1112361538
52 rdf:type schema:PropertyValue
53 N5279182041d746799b499705645fcf41 rdf:first N19eb47b008034b7a8af98894b35e6d5f
54 rdf:rest N912f7e36abdc495fb32c36009d949e04
55 N5baeedb05a0e4f96ba336fac841ee0bc schema:name readcube_id
56 schema:value 9ffc1465d70ef1ee32ba6ee1171785fe44f34065c4ba55d5d4e479c5f799623c
57 rdf:type schema:PropertyValue
58 N5dc20ff5cffa41b3a3b016bc086ca974 schema:name doi
59 schema:value 10.1007/s10924-019-01407-0
60 rdf:type schema:PropertyValue
61 N6f2cdcb230384086a329f233d955091c schema:issueNumber 5
62 rdf:type schema:PublicationIssue
63 N796b64f0e27a490bb2475e75ba89fc45 schema:affiliation https://www.grid.ac/institutes/grid.428369.2
64 schema:familyName Roberts
65 schema:givenName Hester
66 rdf:type schema:Person
67 N912f7e36abdc495fb32c36009d949e04 rdf:first Ne5a8e657aa744710b103f5304a7c63c2
68 rdf:rest N07e9204469bc49cbb11238c76dccab9f
69 N97ca3833bf4843dd8b6bcb54a0b86549 schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 Ne5a8e657aa744710b103f5304a7c63c2 schema:affiliation Nea95944359c1488387ef5f257ea92fef
72 schema:familyName Chiweshe
73 schema:givenName Trevor T.
74 rdf:type schema:Person
75 Nea95944359c1488387ef5f257ea92fef schema:name Institution for Groundwater Studies, University of the Free Sate, Bloemfontein, South Africa
76 rdf:type schema:Organization
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
81 schema:name Macromolecular and Materials Chemistry
82 rdf:type schema:DefinedTerm
83 sg:journal.1297558 schema:issn 1064-7546
84 1572-8919
85 schema:name Journal of Polymers and the Environment
86 rdf:type schema:Periodical
87 https://doi.org/10.1002/app.1974.070180815 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038337825
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1016/j.ijbiomac.2011.11.026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049906271
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1016/j.jtemb.2005.02.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000135360
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/j.progpolymsci.2004.11.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051666301
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/j.progpolymsci.2006.06.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026434192
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/j.scitotenv.2004.01.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039723277
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/j.seppur.2004.08.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049778032
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/s0032-3861(00)00402-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1009257327
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/s1381-5148(01)00113-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033770415
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1021/i300013a033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055529309
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/ie060514s schema:sameAs https://app.dimensions.ai/details/publication/pub.1055600089
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/ie9701579 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055646421
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1080/15226510801913918 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041735451
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1246/bcsj.60.444 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022311269
114 rdf:type schema:CreativeWork
115 https://doi.org/10.4314/wsa.v27i1.5002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006921417
116 rdf:type schema:CreativeWork
117 https://www.grid.ac/institutes/grid.428369.2 schema:alternateName Central University of Technology
118 schema:name Department of life sciences, Central University of Technology, Free State, Bloemfontein, South Africa
119 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...