Electron transfer reactions: generalized spin-boson approach View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2013-03

AUTHORS

M. Merkli, G. P. Berman, R. Sayre

ABSTRACT

We introduce a mathematically rigorous analysis of a generalized spin-boson system for the treatment of a donor–acceptor (reactant-product) quantum system coupled to a thermal quantum noise. The donor/acceptor probability dynamics describes transport reactions in chemical processes in presence of a noisy environment – such as the electron transfer in a photosynthetic reaction center. Besides being rigorous, our analysis has the advantages over previous ones that (1) we include a general, non energy-conserving system-environment interaction, and that (2) we allow for the donor or acceptor to consist of multiple energy levels lying closely together. We establish explicit expressions for the rates and the efficiency (final donor–acceptor population difference) of the reaction. In particular, we show that the rate increases for a multi-level acceptor, but the efficiency does not. More... »

PAGES

890-913

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10910-012-0124-5

DOI

http://dx.doi.org/10.1007/s10910-012-0124-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044075851


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