High-Field ESR and Magnetization Study of a Novel Macrocyclic Chelate Trinuclear Ni(II) Complex View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-04

AUTHORS

Y. Krupskaya, A. Parameswaran, A. Alfonsov, R. Klingeler, V. Kataev, N. Beyer, J. Lach, M. Gressenbuch, B. Kersting, B. Büchner

ABSTRACT

We have investigated magnetic properties of a novel macrocyclic chelate Ni(II) complex [Ni3(L)(OAc)2], by means of the static magnetization M and high field frequency tunable electron spin resonance (HF-ESR). Magnetic field B dependencies of M reveal the magnetic ground state with a total spin S and a strong antiferromagnetic coupling between three Ni(II) ions. HF-ESR measurements at frequencies ν=80–350 GHz and B up to 15 T yield a magnetic anisotropy gap of the order of 60 GHz (2.9 K) and a g-factor of 2.2. In addition, the modelling reveals a positive single ion anisotropy (D>0) corresponding to an easy plane situation for the Ni3 complex. More... »

PAGES

84-87

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10909-009-0095-5

DOI

http://dx.doi.org/10.1007/s10909-009-0095-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009648563


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