Synthesis and Characterization of Charge Transfer Salts Based on DT-TTF and M(dcdmp)2 Complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02

AUTHORS

D. Belo, E. B. Lopes, I. C. Santos, J. C. Dias, M. Figueira, M. Almeida, M. Fourmigué, C. Rovira

ABSTRACT

The charge transfer salts (DT-TTF)2[Ni(dcdmp)2], (DT-TTF)3[Cu(dcdmp)2]2 and (DT-TTF)3[Au(dcdmp)2]2, (dcdmp=2,3-dicyano5,6-dimercaptopyrazine) were obtained by electrocrystallisation and characterized. The Ni compound presents a structure consisting of stacks of fully oxidized donor pairs alternating with dianionic complexes. In the two other compounds the complex is monoanionic, the Au salt presenting a structure with stacks of donors triads alternating with pairs of complexes. All compounds display a semiconductor behavior with the highest electrical conductivity of 6.8 S/cm at room temperature being observed for the Cu salt. More... »

PAGES

353-358

Journal

TITLE

Journal of Low Temperature Physics

ISSUE

3-4

VOLUME

142

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10909-006-9117-8

DOI

http://dx.doi.org/10.1007/s10909-006-9117-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032824538


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