Hierarchical Flower Structured Bi2S3/Reduced Graphene Oxide Nanocomposite for High Electrochemical Performance View Full Text


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Article Info

DATE

2018-01

AUTHORS

Abdul Kalam Noordeen, Sankar Sambasivam, Sengottaiyan Chinnasamy, Jayavel Ramasamy, Thiyagu Subramani

ABSTRACT

A biomolecule assisted synthesis of bismuth sulfide (Bi2S3)/reduced graphene oxide (rGO) composite nanostructures by one-pot hydrothermal method. The structure, morphology and elemental analysis of the synthesized material were studied by X-ray diffractometer (XRD) and high resolution transmission electron microscopy (HR-TEM), field emission scanning electron microscopy (FE-SEM), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). Fourier transform infrared spectroscopy (FT-IR) and Raman spectroscopy attest the reduction of graphene oxide and structural defects respectively. Absorbance and emission responses were studied by UV-vis-NIR and Photoluminescence spectroscopy. Electrochemical performances of the graphene oxide (GO), Bi2S3 and Bi2S3/rGO composite were investigated by Electrochemical workstation. The Bi2S3/rGO composite electrode attained five times higher specific capacitances of 817.6 F g−1 at scan rate of 5 mV s−1 and 680.6 F g−1 at a current density of 1 A g−1 compared to pure Bi2S3 (143.9 F g−1 at 5 mV s−1 and 152.23 F g−1 at 1 A g−1) respectively. Moreover, Bi2S3/rGO composite maintain better cyclic stability with the capacitance retention about 87% over 1000 cycles, and offer a high conductive connection for fast ion diffusion between electrode and electrolyte interface. The strong synergistic effect of the hierarchical flower structured/rGO composite suggest as a promising material for supercapacitor applications. More... »

PAGES

73-83

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10904-017-0701-y

DOI

http://dx.doi.org/10.1007/s10904-017-0701-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1092212095


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10904-017-0701-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10904-017-0701-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10904-017-0701-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10904-017-0701-y'


 

This table displays all metadata directly associated to this object as RDF triples.

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