Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands View Full Text


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Article Info

DATE

2012-01

AUTHORS

Guang-Xiang Liu, Xiao-Chun Zha, Yan Wang, Sadafumi Nishihara, Xiao-Ming Ren

ABSTRACT

A new nickel(II) coordination polymer, Ni2(DBA)2(BIDPE)2(H2O) (1) (H2DBA = 4,4′-methylenedibenzoic acid and BIDPE = 4,4′-bis(imidazole-l-yl)diphenyl ether), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. Complex 1 features a one-dimensional chain structure based on triply bridged binuclear units, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions. Variable-temperature magnetic data shows weak antiferromagnetic behavior in 1. A new nickel(II) coordination polymer, Ni2(DBA)(BIDPE)(H2O), has been prepared by hydrothermal synthesis and features a one-dimensional chain structure based on triply bridged binuclear units. Variable-temperature magnetic data shows weak antiferromagnetic behavior More... »

PAGES

258-263

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10904-011-9530-6

DOI

http://dx.doi.org/10.1007/s10904-011-9530-6

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