A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline View Full Text


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Article Info

DATE

2011-03

AUTHORS

Guang-Xiang Liu, Xiao-Chun Zha, Yan Wang, Sadafumi Nishihara, Xiao-Ming Ren

ABSTRACT

A new chiral Cu(II) complex, Cu3(phen)3(H2O)(BTA)2·13H2O (1) (H3BTA = benzene-1,3,5-triacetate acid and phen = phenanthroline) has been prepared by solvothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in the chiral space group C2 and has similar one-dimensional chains, which are further bridged by μ2-H2O to form a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated. A new chiral Cu(II) complex, Cu3(phen)3(H2O)(BTA)2·13H2O (1) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex shows a two-dimensional layer structure. The nonlinear optical property and magnetic property were investigated. More... »

PAGES

201-206

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http://scigraph.springernature.com/pub.10.1007/s10904-010-9434-x

DOI

http://dx.doi.org/10.1007/s10904-010-9434-x

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