A Novel 3D Europium (III) Coordination Polymer Constructed from 3,5-Pyridinedicarboxylate Acid: Synthesis, Crystal Structure and Emission Spectrum View Full Text


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Article Info

DATE

2008-12

AUTHORS

Guang-Xiang Liu, Hong Chen, Kun Zhu, Xiao-Ming Ren

ABSTRACT

A novel 3D coordination polymer Eu2(PDC)3(H2O)3 (1) has been synthesized by hydrothermal reaction of europium chloride with 3,5-pyridinedicarboxylate acid (H2PDC) under acidic condition (pH 2–3). Complex 1 is a 3D coordination polymer via 1D infinite chains built by the pyridinium moieties of the PDC2− anions. The thermal analyses and luminescent properties of 1 have also been investigated. A novel 3D coordination polymer Eu2(PDC)3(H2O)3 has been synthesized by hydrothermal reaction of europium chloride with 3,5-pyridinedicarboxylate acid under acidic conditions (pH 2–3). The formation of the title complex demonstrates that pH plays an important role during the synthesis. More... »

PAGES

457-462

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10904-008-9222-z

DOI

http://dx.doi.org/10.1007/s10904-008-9222-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045089854


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43 schema:description A novel 3D coordination polymer Eu2(PDC)3(H2O)3 (1) has been synthesized by hydrothermal reaction of europium chloride with 3,5-pyridinedicarboxylate acid (H2PDC) under acidic condition (pH 2–3). Complex 1 is a 3D coordination polymer via 1D infinite chains built by the pyridinium moieties of the PDC2− anions. The thermal analyses and luminescent properties of 1 have also been investigated. A novel 3D coordination polymer Eu2(PDC)3(H2O)3 has been synthesized by hydrothermal reaction of europium chloride with 3,5-pyridinedicarboxylate acid under acidic conditions (pH 2–3). The formation of the title complex demonstrates that pH plays an important role during the synthesis.
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