Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster View Full Text


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Article Info

DATE

2008-06

AUTHORS

Rong-Yi Huang, Xue-Jun Kong, Guang-Xiang Liu

ABSTRACT

A novel 2-fold parallel interpenetrated polymer, Zn2(OH)(pheno)(p-BDC)1.5 · H2O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) was prepared by hydrothermal synthesis and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network. Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster Rong-Yi Huang, Xue-Jun Kong and Guang-Xiang Liu A intriguing feature of complex 1 is a pair of identical 3D single nets is interlocked with each other, thus directly leading to the formation of a 2-fold interpenetrated 3D → 3D architecture. More... »

PAGES

304-308

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10904-008-9199-7

DOI

http://dx.doi.org/10.1007/s10904-008-9199-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018209951


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