Anthraimidazoledione Based Reversible and Reusable Selective Chemosensors for Fluoride Ion: Naked-Eye, Colorimetric and Fluorescence “ON-OFF” View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-05

AUTHORS

Bhaswati Bhattacharyya, Arijit Kundu, Nikhil Guchhait, Kaliprasanna Dhara

ABSTRACT

Novel anthraimidazoledione-based compounds (1-3) are synthesized as selective colorimetric and fluorescent sensors for fluoride ion. The binding properties of the probes (1-3) are studied with different anions in acetonitrile solvent. Spectral red shifts in the absorption spectra and 'turn-off' emission are observed when fluoride is added to 1-3. The striking green to orange color change in the ambient light is thought to be due to the deprotonation of the N-H proton of the imidazole moiety of the probes by the basic F- ion. Interestingly, in all three cases the nonfluorescent probe-F- solutions, on treatment with copper perchlorate, show distinct color change from orange to golden yellow with resumption of fluorescence intensity. Furthermore, the reversibility of sensors (1-3) for the detection of F- ion is tested for four cycles indicating that "ON-OFF-ON" mechanism is operative. Test strip based on sensor 2 acts as a reusable cost-effective F- sensor. More... »

PAGES

1041-1049

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10895-017-2038-x

DOI

http://dx.doi.org/10.1007/s10895-017-2038-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1083738686

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/28185038


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