Calix[4]arene Based Dual Fluorescent Sensor for Al3+ and S2O72− View Full Text


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Article Info

DATE

2016-06-20

AUTHORS

Shahabuddin Memon, Ashfaque Ali Bhatti, Asif Ali Bhatti, Ümmühan Ocak, Miraç Ocak

ABSTRACT

Specific functionalized calix[4]arene based fluorescent chemosensor was synthesized for cations and anions binding efficiency examination. Receptor C4MA displayed strong affinity for Al3+and S2O72− with enhanced fluorescence intensity. The selective response of C4MA was investigated in the presence of different co-existing competing ions. The limit of detection (LOD) of Al3+and S2O72− was calculated as 2.8 × 10−6 M and 2.6 × 10−7 M respectively. Sensor C4MA forms (1:1) stoichiometric complex with both Al3+ and S2O72− and their binding constants were calculated as 12.1 × 104 and 8.3 × 103 respectively. Complexes were also characterized through FT-IR spectroscopy.Graphical Abstractᅟ More... »

PAGES

1591-1599

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10895-016-1843-y

DOI

http://dx.doi.org/10.1007/s10895-016-1843-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042541540

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/27324953


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