Calix[4]arene Based Highly Efficient Fluorescent Sensor for Au3+ and I− View Full Text


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Article Info

DATE

2015-08-20

AUTHORS

Shahabuddin Memon, Ashfaque Ali Bhatti, Asif Ali Bhatti, Ümmühan Ocak, Miraç Ocak

ABSTRACT

This approach disclose the selective fluorogenic ion sensing ability of 5,11,17,23-tetratertbutyl-25,27-bis((2hydroxynaphthylimino)1,2-ethylenediaminecarbonylmethoxy)-26,28 dihydroxycalix[4]arene (C4NSB). Binding property of receptor probed by using selected various cations and anions with conferring of results that demonstrates ‘turn-off’ fluorescence response and significantly high chromogenic selectivity toward Au3+ and I−. Furthermore, selective nature of receptor was investigated in the presence of different co-existing competing ions. The limit of detection (LOD) for Au3+ and I− was determined as 1.5 × 10−5 and 4.5 × 10−6 M respectively. Receptor C4NSB form (1:1) stoichiometric complex with both ions and their binding constants were calculated as 8.0 × 102 for Au3+ and 15.6 × 102 M−1 for I−. Complexes were also characterized through FT-IR spectroscopy. More... »

PAGES

1507-1515

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10895-015-1642-x

DOI

http://dx.doi.org/10.1007/s10895-015-1642-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007025993

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/26289105


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