Pyrene-1-Carboxylate in Water and Glycerol Solutions: Origin of the Change of pK Upon Excitation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-01

AUTHORS

Nathaniel V. Nucci, Bogumil Zelent, Jane M. Vanderkooi

ABSTRACT

Pyrene-1-carboxy acid has a pK of 4 in the ground state, and a pK of 8 in the excited state. Fluorescence spectra of the acid and base forms are presented as a function of solvent and temperature. Ab initio quantum calculations indicate that the bond between the ring system and the carboxyl group has aromatic character that becomes stronger upon excitation. This stabilization helps to account for the increase in pK upon excitation. More... »

PAGES

41-49

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10895-007-0233-x

DOI

http://dx.doi.org/10.1007/s10895-007-0233-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043283050

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/17846872


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