Liquid-crystal state in the system polysaccharide-mesophasogenic solvent View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-01

AUTHORS

A. B. Shipovskaya, G. N. Timofeev

ABSTRACT

Data on the influence of vapors of nitromethane — a mesophasogenic solvent, i.e., a solvent forming with a polymer a lyotropic liquid-crystal phase — on the structure of acetate fibers are presented. It has been established that nitromethane in the vaporous state initiates in the polymer matrix orientation processes: induced anisotropy, spontaneous elongation of the fiber (which, in terms of Flory, is considered to be the transition to the nematic phase), as well as the process inverse to the self-elongation discovered for the first time, etc. It has been shown that the realization of both the direct and inverse processes of spontaneous deformation of cellulose acetate in mesophasogenic solvent vapors is associated with the optical asymmetry, i.e., the optical activity of the polysaccharide. More... »

PAGES

143-151

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10891-006-0078-1

DOI

http://dx.doi.org/10.1007/s10891-006-0078-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003796921


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