Synthesis and Characterization of a Novel POM-Based Compound Contained Bi-Capped Bi Keggin Anion and Organic Ligand for Multifunctional Catalytic Property View Full Text


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Article Info

DATE

2019-03-02

AUTHORS

Shu Y. Shi, Dan Bai, Ling Y. Chen, Jia Q. Liang, Yu X. Ma, Wei Jiang, Jun Zhang, Xiao B. Cui

ABSTRACT

A new organic–inorganic hybrid compound contained bi-capped Bi Keggin anion, [biim][PMo1VMo11VIBi1.24O40]·3H2O (1) (biim = biimidazole) has been firstly synthesized and characterized by IR, UV–Vis, XRD, XPS, elemental analyses, fluorescent spectrum and TG analysis. Compound 1 exhibits a novel 2-D supramolecular network structure constructed from {PMo1VMo11VIBi1.24O40} anions by O···O interactions, and further extends a 3-D supramolecular framework by bridges of biimidazole with N–H···O hydrogen bonding interactions. The compound 1 performs well catalytic property for epoxidation of styrene to styrene oxide. Moreover, compound 1 displays excellent photodegradation activity for methyl orange dye. More... »

PAGES

1-7

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-019-01525-8

DOI

http://dx.doi.org/10.1007/s10876-019-01525-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112505143


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10876-019-01525-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10876-019-01525-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10876-019-01525-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10876-019-01525-8'


 

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