Identification of an Eight-Electron Superatomic Cluster and Its Alloy in One Co-crystal Structure View Full Text


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Article Info

DATE

2018-09

AUTHORS

Jian-Hong Liao, Samia Kahlal, Yu-Chiao Liu, Ming-Hsi Chiang, Jean-Yves Saillard, C. W. Liu

ABSTRACT

Herein we report a crystal structure of [Au0.5Ag0.5@Ag20{S2P(OiPr)2}12](PF6) [Cl@Ag8{S2P(OiPr)2}6](PF6) (1), which compositions were supported by positive-mode electrospray ionization mass spectrometry. The structural elucidation indicates that the encapsulated atom of an Ag13 the entered icosahedron can be replaced by a gold atom. Surprisingly, the capping Ag atoms on the surface of an icosahedron in 1 reveal a different arrangement from the previously reported [Ag21{S2P(OiPr)2}12](PF6) of C3 symmetry. Besides, the preference for the central silver atom being oxidized by Au(I) is rationalized by the DFT calculations on three different computed [AuAg20{S2PH2}12]+ models having C1, C3, and T symmetry, respectively. More... »

PAGES

827-835

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-018-1353-y

DOI

http://dx.doi.org/10.1007/s10876-018-1353-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101243240


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Turtle is a human-readable linked data format.

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This table displays all metadata directly associated to this object as RDF triples.

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