Formation of Silicon-Containing Polyoxoniobates from Hexaniobate Under High Temperature Conditions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-03

AUTHORS

P. A. Abramov, A. T. Davletgildeeva, M. N. Sokolov

ABSTRACT

Hydrothermal reaction of K7H[Nb6O19]·13H2O with Na2SiO3·9H2O (220 °C, 24 h) produces a lacunary siliconiobate [Si4Nb16O56]16−, which was isolated as mixed salt NaK8H6[Na@Si4Nb16O56]·26H2O (1). Changing the silicon source to Ph2Si(OH)2 under the same conditions slightly improves the yield of [Si4Nb16O56]16−, which was isolated as K14H[K@Si4Nb16O56]·26H2O (2). Extending the reaction time leads to rearrangement of [Si4Nb16O56]16− into Keggin-type silicododecaniobate [SiNb12O40]16−, which was isolated and characterized as K8H2(Nb2O2)[SiNb12O40]·20H2O (3). The complexes were characterized by X-ray single crystal analysis, elemental analysis, thermogravimetry, 29Si NMR. More... »

PAGES

735-744

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-016-1121-9

DOI

http://dx.doi.org/10.1007/s10876-016-1121-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002325420


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