Synthesis of Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (Im = 1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-01

AUTHORS

M. N. Sokolov, A. V. Rogachev, A. V. Virovets, D. A. Piryazev, V. P. Fedin

ABSTRACT

Reaction of 1D cluster coordination polymer Mo3S7Br4 with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and AlBr3 in 2:1 molar ratio affords Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (1) in high yield. X-ray structure of 1·CH3CN is reported.

PAGES

33-40

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-014-0739-8

DOI

http://dx.doi.org/10.1007/s10876-014-0739-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041752199


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