Oxo-Centered Trinuclear Chromium(III) Complexes with Both Carboxylate and Amidoximate Ligands View Full Text


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Article Info

DATE

2014-05

AUTHORS

Adrian-Raul Tomsa, Yanling Li, Sébastien Blanchard, Patrick Herson, Kamal Boubekeur, Pierre Gouzerh, Anna Proust

ABSTRACT

Compounds [Cr3III(μ3-O)(O2CPh)5(H2N-sao)(EtOH)2]·EtOH (1·EtOH) and [Cr3III(μ3-O)(O2CPh)3(H2N-pao)3]NO3·H2N-paoH·EtOH (2·NO3·H2N-paoH·EtOH) have been obtained either in a sequential one-pot, two-step procedure in which Cr(NO3)3·9H2O is first reacted with sodium benzoate in ethanol under reflux, followed by the addition of salicylamidoxime (H2N-saoH2) or pyridine-2-amidoxime (H2N-paoH), or in a one-step protocol starting from [Cr3III(μ3-O)(O2CPh)6(EtOH)3]NO3. They were characterized by single-crystal X-ray diffraction, magnetometry and EPR spectroscopy. Complexes 1 and 2 are derived from the parent complex [Cr3III(μ3-O)(O2CPh)6(EtOH)3]+ by replacement of one and three benzoate ligands, respectively, by oximate ligands. The salicylamidoximate and pyridine-2-amidoximate ligands display a tridentate coordination mode with the N–O oximate group bridging a pair of Cr atoms and the additional ligating atom substituting for an ethanol ligand of the parent complex. In both cases susceptibility, magnetization and EPR data reveal a ST = 1/2 ground state with a nearly isotropic g-tensor. More... »

PAGES

825-838

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-013-0669-x

DOI

http://dx.doi.org/10.1007/s10876-013-0669-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047517512


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10876-013-0669-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10876-013-0669-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10876-013-0669-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10876-013-0669-x'


 

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