Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure and Regioselective Thermal Rearrangements of Os3(CO)10{μ-Ph2PCH(Me)PPh2} View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-09

AUTHORS

Shishir Ghosh, Graeme Hogarth, Shariff E. Kabir, Arun K. Raha, Michael G. Richmond, Jagodish C. Sarker

ABSTRACT

Addition of 1,1-bis(diphenylphosphino)ethane, Ph2PCH(Me)PPh2, to Os3(CO)12 in benzene at 60 °C in the presence of Me3NO affords Os3(CO)10{μ-Ph2PCH(Me)PPh2} (1) in almost quantitative yield. Thermolysis of 1 in boiling toluene gives the expected electronically-unsaturated 46-electron triosmium cluster Os3(CO)8{μ3-Ph2PCH(Me)P(Ph)C6H4}(μ-H) (2) as the major product formed from the regioselective activation of a phenyl ring lying anti to the methyl group in 1. A second minor product is Os3(CO)8{μ3-Ph2PC(Me)P(Ph)C6H4}(μ-H)2 (3) resulting from the activation of methine and phenyl protons. This complex contains an unusual semi-bridging tertiary phosphine ligand characterized by short [2.398(1) Å] and long [2.872(1) Å] osmium–phosphorus interactions which structurally resembles an intermediate during phosphine migration across a metal–metal edge. The extent of the bonding in this potential three-center, two-electron interaction was examined by electronic structure calculations. The Wiberg bond index for the short Os(1)–P(1) bond is as expected but the long Os(3)–P(1) interaction is nearly an order of magnitude smaller, which suggests that there is no significant interaction between the Os(3) and P(1) centers. Prolonged heating of 2 in boiling toluene leads to the formation of Os3(CO)7(η6-C6H5CH3){μ3-PhPCH(Me)P(Ph)C6H4} (4), while in octane Os3(CO)9{μ3-PhPCH(Me)P(Ph)C6H4} (5) is generated. Both contain the 6-electron μ3-PhPCH(Me)P(Ph)C6H4 ligand formed as a result of carbon–phosphorus bond cleavage, while in 4 toluene has displaced three carbonyls. The molecular structures of 1–4 have been determined by single crystal X-ray diffraction analysis. More... »

PAGES

781-798

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-012-0471-1

DOI

http://dx.doi.org/10.1007/s10876-012-0471-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025995766


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University College London", 
          "id": "https://www.grid.ac/institutes/grid.83440.3b", 
          "name": [
            "Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh", 
            "Department of Chemistry, University College London, 20 Gordon Street, WC1H 0AJ, London, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ghosh", 
        "givenName": "Shishir", 
        "id": "sg:person.016155403257.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016155403257.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University College London", 
          "id": "https://www.grid.ac/institutes/grid.83440.3b", 
          "name": [
            "Department of Chemistry, University College London, 20 Gordon Street, WC1H 0AJ, London, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hogarth", 
        "givenName": "Graeme", 
        "id": "sg:person.0742230216.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0742230216.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Jahangirnagar University", 
          "id": "https://www.grid.ac/institutes/grid.411808.4", 
          "name": [
            "Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kabir", 
        "givenName": "Shariff E.", 
        "id": "sg:person.01370346527.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01370346527.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Jahangirnagar University", 
          "id": "https://www.grid.ac/institutes/grid.411808.4", 
          "name": [
            "Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Raha", 
        "givenName": "Arun K.", 
        "id": "sg:person.013533100437.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013533100437.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of North Texas", 
          "id": "https://www.grid.ac/institutes/grid.266869.5", 
          "name": [
            "Department of Chemistry, University of North Texas, 1155 Union Circle, Box 305070, 76203, Denton, TX, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Richmond", 
        "givenName": "Michael G.", 
        "id": "sg:person.014740162521.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014740162521.20"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Jahangirnagar University", 
          "id": "https://www.grid.ac/institutes/grid.411808.4", 
          "name": [
            "Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sarker", 
        "givenName": "Jagodish C.", 
        "id": "sg:person.010664036065.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010664036065.21"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s11172-008-0299-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000596984", 
          "https://doi.org/10.1007/s11172-008-0299-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-008-0299-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000596984", 
          "https://doi.org/10.1007/s11172-008-0299-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-328x(00)87268-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001075926"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)93517-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001216643"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39840000949", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002018973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0065-3055(08)60488-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002506734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ica.2005.12.053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003299654"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b314734g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003376524"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1009551905096", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004434831", 
          "https://doi.org/10.1023/a:1009551905096"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a902139f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004494539"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v02-127", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007754419"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b210114a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009368993"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/cs9831200099", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009880736"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)81640-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010132425"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b616847g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010313880"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b301251d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010910194"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ccr.2008.08.013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011922257"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)92368-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012825534"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-328x(85)80075-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012857914"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-8545(88)85014-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013888849"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200300627", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014036258"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/dt9930000827", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014315084"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-328x(87)85157-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014572067"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/jr9620001490", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014599984"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b606665h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015308731"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2008.08.032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016362152"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tetlet.2003.09.117", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017447126"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tetlet.2003.09.117", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017447126"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39900000053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018675914"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b001080o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020737552"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1071/ch9851301", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023677982"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-328x(84)80667-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025819826"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/dt9960002395", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026897814"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2007.09.024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029007295"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39870001829", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029011873"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0277-5387(00)83787-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033880636"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39860000540", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034253209"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/dt9840000863", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035235465"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11243-008-9081-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035578362", 
          "https://doi.org/10.1007/s11243-008-9081-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19791120226", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036224282"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1015715623361", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037615736", 
          "https://doi.org/10.1023/a:1015715623361"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2005.03.041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039184864"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2008.12.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040005750"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19590921221", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040328428"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-328x(00)86022-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041131285"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/dt9930001671", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041264097"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2008.10.030", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041758581"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-328x(84)80525-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042845915"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.464913", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042899913"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39850001280", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043762861"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-328x(95)06024-q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043766747"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2010.11.022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044308716"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)81432-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045512320"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39920000632", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047198058"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39820000286", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048669976"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v05-254", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050072626"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1016627113620", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050101650", 
          "https://doi.org/10.1023/a:1016627113620"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200305419", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050463892"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.19840670818", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050519394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00088a005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053814061"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00030a006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053814163"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0207000", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055554700"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic0207000", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055554700"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50003a016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055566522"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50110a022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055572851"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50173a038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055577052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50212a079", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055579956"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50226a018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055581032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00301a018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055721582"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00399a059", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055729393"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om00006a026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056261693"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om000322b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056263564"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om00142a009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056269484"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om0505413", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056274155"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om100475v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056276012"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om100783f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056276238"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om100894w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056276320"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om7007716", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056280540"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/om900285e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056282016"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.37.785", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060546104"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.37.785", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060546104"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2012-09", 
    "datePublishedReg": "2012-09-01", 
    "description": "Addition of 1,1-bis(diphenylphosphino)ethane, Ph2PCH(Me)PPh2, to Os3(CO)12 in benzene at 60 \u00b0C in the presence of Me3NO affords Os3(CO)10{\u03bc-Ph2PCH(Me)PPh2} (1) in almost quantitative yield. Thermolysis of 1 in boiling toluene gives the expected electronically-unsaturated 46-electron triosmium cluster Os3(CO)8{\u03bc3-Ph2PCH(Me)P(Ph)C6H4}(\u03bc-H) (2) as the major product formed from the regioselective activation of a phenyl ring lying anti to the methyl group in 1. A second minor product is Os3(CO)8{\u03bc3-Ph2PC(Me)P(Ph)C6H4}(\u03bc-H)2 (3) resulting from the activation of methine and phenyl protons. This complex contains an unusual semi-bridging tertiary phosphine ligand characterized by short [2.398(1) \u00c5] and long [2.872(1) \u00c5] osmium\u2013phosphorus interactions which structurally resembles an intermediate during phosphine migration across a metal\u2013metal edge. The extent of the bonding in this potential three-center, two-electron interaction was examined by electronic structure calculations. The Wiberg bond index for the short Os(1)\u2013P(1) bond is as expected but the long Os(3)\u2013P(1) interaction is nearly an order of magnitude smaller, which suggests that there is no significant interaction between the Os(3) and P(1) centers. Prolonged heating of 2 in boiling toluene leads to the formation of Os3(CO)7(\u03b76-C6H5CH3){\u03bc3-PhPCH(Me)P(Ph)C6H4} (4), while in octane Os3(CO)9{\u03bc3-PhPCH(Me)P(Ph)C6H4} (5) is generated. Both contain the 6-electron \u03bc3-PhPCH(Me)P(Ph)C6H4 ligand formed as a result of carbon\u2013phosphorus bond cleavage, while in 4 toluene has displaced three carbonyls. The molecular structures of 1\u20134 have been determined by single crystal X-ray diffraction analysis.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10876-012-0471-1", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.3084090", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1130720", 
        "issn": [
          "1040-7278", 
          "1572-8862"
        ], 
        "name": "Journal of Cluster Science", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "23"
      }
    ], 
    "name": "Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure and Regioselective Thermal Rearrangements of Os3(CO)10{\u03bc-Ph2PCH(Me)PPh2}", 
    "pagination": "781-798", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "7bd7db3ec80f7196fdba1b8cfea4efd44786fc825d89809c3d1b8abc913589d7"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10876-012-0471-1"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1025995766"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10876-012-0471-1", 
      "https://app.dimensions.ai/details/publication/pub.1025995766"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:46", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000488.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/s10876-012-0471-1"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10876-012-0471-1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10876-012-0471-1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10876-012-0471-1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10876-012-0471-1'


 

This table displays all metadata directly associated to this object as RDF triples.

344 TRIPLES      21 PREDICATES      105 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10876-012-0471-1 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N18b1ee5b55244af3869ba2aeba82ac7a
4 schema:citation sg:pub.10.1007/s11172-008-0299-x
5 sg:pub.10.1007/s11243-008-9081-z
6 sg:pub.10.1023/a:1009551905096
7 sg:pub.10.1023/a:1015715623361
8 sg:pub.10.1023/a:1016627113620
9 https://doi.org/10.1002/anie.200300627
10 https://doi.org/10.1002/cber.19590921221
11 https://doi.org/10.1002/cber.19791120226
12 https://doi.org/10.1002/chem.200305419
13 https://doi.org/10.1002/hlca.19840670818
14 https://doi.org/10.1016/0010-8545(88)85014-8
15 https://doi.org/10.1016/0022-328x(84)80525-2
16 https://doi.org/10.1016/0022-328x(84)80667-1
17 https://doi.org/10.1016/0022-328x(85)80075-9
18 https://doi.org/10.1016/0022-328x(87)85157-4
19 https://doi.org/10.1016/0022-328x(95)06024-q
20 https://doi.org/10.1016/j.ccr.2008.08.013
21 https://doi.org/10.1016/j.ica.2005.12.053
22 https://doi.org/10.1016/j.jorganchem.2005.03.041
23 https://doi.org/10.1016/j.jorganchem.2007.09.024
24 https://doi.org/10.1016/j.jorganchem.2008.08.032
25 https://doi.org/10.1016/j.jorganchem.2008.10.030
26 https://doi.org/10.1016/j.jorganchem.2008.12.005
27 https://doi.org/10.1016/j.jorganchem.2010.11.022
28 https://doi.org/10.1016/j.tetlet.2003.09.117
29 https://doi.org/10.1016/s0020-1693(00)81432-2
30 https://doi.org/10.1016/s0020-1693(00)81640-0
31 https://doi.org/10.1016/s0020-1693(00)92368-5
32 https://doi.org/10.1016/s0020-1693(00)93517-5
33 https://doi.org/10.1016/s0022-328x(00)86022-2
34 https://doi.org/10.1016/s0022-328x(00)87268-x
35 https://doi.org/10.1016/s0065-3055(08)60488-8
36 https://doi.org/10.1016/s0277-5387(00)83787-0
37 https://doi.org/10.1021/cr00030a006
38 https://doi.org/10.1021/cr00088a005
39 https://doi.org/10.1021/ic0207000
40 https://doi.org/10.1021/ic50003a016
41 https://doi.org/10.1021/ic50110a022
42 https://doi.org/10.1021/ic50173a038
43 https://doi.org/10.1021/ic50212a079
44 https://doi.org/10.1021/ic50226a018
45 https://doi.org/10.1021/ja00301a018
46 https://doi.org/10.1021/ja00399a059
47 https://doi.org/10.1021/om00006a026
48 https://doi.org/10.1021/om000322b
49 https://doi.org/10.1021/om00142a009
50 https://doi.org/10.1021/om0505413
51 https://doi.org/10.1021/om100475v
52 https://doi.org/10.1021/om100783f
53 https://doi.org/10.1021/om100894w
54 https://doi.org/10.1021/om7007716
55 https://doi.org/10.1021/om900285e
56 https://doi.org/10.1039/a902139f
57 https://doi.org/10.1039/b001080o
58 https://doi.org/10.1039/b210114a
59 https://doi.org/10.1039/b301251d
60 https://doi.org/10.1039/b314734g
61 https://doi.org/10.1039/b606665h
62 https://doi.org/10.1039/b616847g
63 https://doi.org/10.1039/c39820000286
64 https://doi.org/10.1039/c39840000949
65 https://doi.org/10.1039/c39850001280
66 https://doi.org/10.1039/c39860000540
67 https://doi.org/10.1039/c39870001829
68 https://doi.org/10.1039/c39900000053
69 https://doi.org/10.1039/c39920000632
70 https://doi.org/10.1039/cs9831200099
71 https://doi.org/10.1039/dt9840000863
72 https://doi.org/10.1039/dt9930000827
73 https://doi.org/10.1039/dt9930001671
74 https://doi.org/10.1039/dt9960002395
75 https://doi.org/10.1039/jr9620001490
76 https://doi.org/10.1063/1.464913
77 https://doi.org/10.1071/ch9851301
78 https://doi.org/10.1103/physrevb.37.785
79 https://doi.org/10.1107/s0108767307043930
80 https://doi.org/10.1139/v02-127
81 https://doi.org/10.1139/v05-254
82 schema:datePublished 2012-09
83 schema:datePublishedReg 2012-09-01
84 schema:description Addition of 1,1-bis(diphenylphosphino)ethane, Ph2PCH(Me)PPh2, to Os3(CO)12 in benzene at 60 °C in the presence of Me3NO affords Os3(CO)10{μ-Ph2PCH(Me)PPh2} (1) in almost quantitative yield. Thermolysis of 1 in boiling toluene gives the expected electronically-unsaturated 46-electron triosmium cluster Os3(CO)8{μ3-Ph2PCH(Me)P(Ph)C6H4}(μ-H) (2) as the major product formed from the regioselective activation of a phenyl ring lying anti to the methyl group in 1. A second minor product is Os3(CO)8{μ3-Ph2PC(Me)P(Ph)C6H4}(μ-H)2 (3) resulting from the activation of methine and phenyl protons. This complex contains an unusual semi-bridging tertiary phosphine ligand characterized by short [2.398(1) Å] and long [2.872(1) Å] osmium–phosphorus interactions which structurally resembles an intermediate during phosphine migration across a metal–metal edge. The extent of the bonding in this potential three-center, two-electron interaction was examined by electronic structure calculations. The Wiberg bond index for the short Os(1)–P(1) bond is as expected but the long Os(3)–P(1) interaction is nearly an order of magnitude smaller, which suggests that there is no significant interaction between the Os(3) and P(1) centers. Prolonged heating of 2 in boiling toluene leads to the formation of Os3(CO)7(η6-C6H5CH3){μ3-PhPCH(Me)P(Ph)C6H4} (4), while in octane Os3(CO)9{μ3-PhPCH(Me)P(Ph)C6H4} (5) is generated. Both contain the 6-electron μ3-PhPCH(Me)P(Ph)C6H4 ligand formed as a result of carbon–phosphorus bond cleavage, while in 4 toluene has displaced three carbonyls. The molecular structures of 1–4 have been determined by single crystal X-ray diffraction analysis.
85 schema:genre research_article
86 schema:inLanguage en
87 schema:isAccessibleForFree false
88 schema:isPartOf N270aa4409eea421397263b23e725d2f8
89 Nc12537135b164a8aba3642ddc978ab95
90 sg:journal.1130720
91 schema:name Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure and Regioselective Thermal Rearrangements of Os3(CO)10{μ-Ph2PCH(Me)PPh2}
92 schema:pagination 781-798
93 schema:productId N00d72f49712040ca8d59e5cf69d6a0db
94 N83d8193fb7ab480b81aafb78e90edd12
95 Na44f6a469ff245448b1c1ac4fe524bc0
96 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025995766
97 https://doi.org/10.1007/s10876-012-0471-1
98 schema:sdDatePublished 2019-04-10T15:46
99 schema:sdLicense https://scigraph.springernature.com/explorer/license/
100 schema:sdPublisher N82ee75efddf64eb5b563673a2fac325a
101 schema:url http://link.springer.com/10.1007/s10876-012-0471-1
102 sgo:license sg:explorer/license/
103 sgo:sdDataset articles
104 rdf:type schema:ScholarlyArticle
105 N00d72f49712040ca8d59e5cf69d6a0db schema:name doi
106 schema:value 10.1007/s10876-012-0471-1
107 rdf:type schema:PropertyValue
108 N18b1ee5b55244af3869ba2aeba82ac7a rdf:first sg:person.016155403257.55
109 rdf:rest N7b1335e25090476e9340282996a4a0ec
110 N270aa4409eea421397263b23e725d2f8 schema:issueNumber 3
111 rdf:type schema:PublicationIssue
112 N62605f21fb17494fbb39ef5dd1e4a773 rdf:first sg:person.014740162521.20
113 rdf:rest Ncdefa32e00834b33b2944308227da7e2
114 N752b44f4296f427999804a9353d8db4e rdf:first sg:person.013533100437.27
115 rdf:rest N62605f21fb17494fbb39ef5dd1e4a773
116 N7b1335e25090476e9340282996a4a0ec rdf:first sg:person.0742230216.21
117 rdf:rest Ncdac3ea4009d42e99158ba114efbce04
118 N82ee75efddf64eb5b563673a2fac325a schema:name Springer Nature - SN SciGraph project
119 rdf:type schema:Organization
120 N83d8193fb7ab480b81aafb78e90edd12 schema:name dimensions_id
121 schema:value pub.1025995766
122 rdf:type schema:PropertyValue
123 Na44f6a469ff245448b1c1ac4fe524bc0 schema:name readcube_id
124 schema:value 7bd7db3ec80f7196fdba1b8cfea4efd44786fc825d89809c3d1b8abc913589d7
125 rdf:type schema:PropertyValue
126 Nc12537135b164a8aba3642ddc978ab95 schema:volumeNumber 23
127 rdf:type schema:PublicationVolume
128 Ncdac3ea4009d42e99158ba114efbce04 rdf:first sg:person.01370346527.86
129 rdf:rest N752b44f4296f427999804a9353d8db4e
130 Ncdefa32e00834b33b2944308227da7e2 rdf:first sg:person.010664036065.21
131 rdf:rest rdf:nil
132 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
133 schema:name Chemical Sciences
134 rdf:type schema:DefinedTerm
135 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
136 schema:name Inorganic Chemistry
137 rdf:type schema:DefinedTerm
138 sg:grant.3084090 http://pending.schema.org/fundedItem sg:pub.10.1007/s10876-012-0471-1
139 rdf:type schema:MonetaryGrant
140 sg:journal.1130720 schema:issn 1040-7278
141 1572-8862
142 schema:name Journal of Cluster Science
143 rdf:type schema:Periodical
144 sg:person.010664036065.21 schema:affiliation https://www.grid.ac/institutes/grid.411808.4
145 schema:familyName Sarker
146 schema:givenName Jagodish C.
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010664036065.21
148 rdf:type schema:Person
149 sg:person.013533100437.27 schema:affiliation https://www.grid.ac/institutes/grid.411808.4
150 schema:familyName Raha
151 schema:givenName Arun K.
152 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013533100437.27
153 rdf:type schema:Person
154 sg:person.01370346527.86 schema:affiliation https://www.grid.ac/institutes/grid.411808.4
155 schema:familyName Kabir
156 schema:givenName Shariff E.
157 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01370346527.86
158 rdf:type schema:Person
159 sg:person.014740162521.20 schema:affiliation https://www.grid.ac/institutes/grid.266869.5
160 schema:familyName Richmond
161 schema:givenName Michael G.
162 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014740162521.20
163 rdf:type schema:Person
164 sg:person.016155403257.55 schema:affiliation https://www.grid.ac/institutes/grid.83440.3b
165 schema:familyName Ghosh
166 schema:givenName Shishir
167 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016155403257.55
168 rdf:type schema:Person
169 sg:person.0742230216.21 schema:affiliation https://www.grid.ac/institutes/grid.83440.3b
170 schema:familyName Hogarth
171 schema:givenName Graeme
172 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0742230216.21
173 rdf:type schema:Person
174 sg:pub.10.1007/s11172-008-0299-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1000596984
175 https://doi.org/10.1007/s11172-008-0299-x
176 rdf:type schema:CreativeWork
177 sg:pub.10.1007/s11243-008-9081-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1035578362
178 https://doi.org/10.1007/s11243-008-9081-z
179 rdf:type schema:CreativeWork
180 sg:pub.10.1023/a:1009551905096 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004434831
181 https://doi.org/10.1023/a:1009551905096
182 rdf:type schema:CreativeWork
183 sg:pub.10.1023/a:1015715623361 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037615736
184 https://doi.org/10.1023/a:1015715623361
185 rdf:type schema:CreativeWork
186 sg:pub.10.1023/a:1016627113620 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050101650
187 https://doi.org/10.1023/a:1016627113620
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1002/anie.200300627 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014036258
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1002/cber.19590921221 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040328428
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1002/cber.19791120226 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036224282
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1002/chem.200305419 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050463892
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1002/hlca.19840670818 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050519394
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1016/0010-8545(88)85014-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013888849
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1016/0022-328x(84)80525-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042845915
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1016/0022-328x(84)80667-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025819826
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1016/0022-328x(85)80075-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012857914
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1016/0022-328x(87)85157-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014572067
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1016/0022-328x(95)06024-q schema:sameAs https://app.dimensions.ai/details/publication/pub.1043766747
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1016/j.ccr.2008.08.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011922257
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1016/j.ica.2005.12.053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003299654
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1016/j.jorganchem.2005.03.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039184864
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1016/j.jorganchem.2007.09.024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029007295
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1016/j.jorganchem.2008.08.032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016362152
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1016/j.jorganchem.2008.10.030 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041758581
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1016/j.jorganchem.2008.12.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040005750
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1016/j.jorganchem.2010.11.022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044308716
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1016/j.tetlet.2003.09.117 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017447126
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1016/s0020-1693(00)81432-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045512320
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1016/s0020-1693(00)81640-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010132425
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1016/s0020-1693(00)92368-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012825534
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1016/s0020-1693(00)93517-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001216643
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1016/s0022-328x(00)86022-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041131285
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1016/s0022-328x(00)87268-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1001075926
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1016/s0065-3055(08)60488-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002506734
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1016/s0277-5387(00)83787-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033880636
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1021/cr00030a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053814163
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1021/cr00088a005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053814061
248 rdf:type schema:CreativeWork
249 https://doi.org/10.1021/ic0207000 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055554700
250 rdf:type schema:CreativeWork
251 https://doi.org/10.1021/ic50003a016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055566522
252 rdf:type schema:CreativeWork
253 https://doi.org/10.1021/ic50110a022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055572851
254 rdf:type schema:CreativeWork
255 https://doi.org/10.1021/ic50173a038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055577052
256 rdf:type schema:CreativeWork
257 https://doi.org/10.1021/ic50212a079 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055579956
258 rdf:type schema:CreativeWork
259 https://doi.org/10.1021/ic50226a018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055581032
260 rdf:type schema:CreativeWork
261 https://doi.org/10.1021/ja00301a018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055721582
262 rdf:type schema:CreativeWork
263 https://doi.org/10.1021/ja00399a059 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055729393
264 rdf:type schema:CreativeWork
265 https://doi.org/10.1021/om00006a026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056261693
266 rdf:type schema:CreativeWork
267 https://doi.org/10.1021/om000322b schema:sameAs https://app.dimensions.ai/details/publication/pub.1056263564
268 rdf:type schema:CreativeWork
269 https://doi.org/10.1021/om00142a009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056269484
270 rdf:type schema:CreativeWork
271 https://doi.org/10.1021/om0505413 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056274155
272 rdf:type schema:CreativeWork
273 https://doi.org/10.1021/om100475v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056276012
274 rdf:type schema:CreativeWork
275 https://doi.org/10.1021/om100783f schema:sameAs https://app.dimensions.ai/details/publication/pub.1056276238
276 rdf:type schema:CreativeWork
277 https://doi.org/10.1021/om100894w schema:sameAs https://app.dimensions.ai/details/publication/pub.1056276320
278 rdf:type schema:CreativeWork
279 https://doi.org/10.1021/om7007716 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056280540
280 rdf:type schema:CreativeWork
281 https://doi.org/10.1021/om900285e schema:sameAs https://app.dimensions.ai/details/publication/pub.1056282016
282 rdf:type schema:CreativeWork
283 https://doi.org/10.1039/a902139f schema:sameAs https://app.dimensions.ai/details/publication/pub.1004494539
284 rdf:type schema:CreativeWork
285 https://doi.org/10.1039/b001080o schema:sameAs https://app.dimensions.ai/details/publication/pub.1020737552
286 rdf:type schema:CreativeWork
287 https://doi.org/10.1039/b210114a schema:sameAs https://app.dimensions.ai/details/publication/pub.1009368993
288 rdf:type schema:CreativeWork
289 https://doi.org/10.1039/b301251d schema:sameAs https://app.dimensions.ai/details/publication/pub.1010910194
290 rdf:type schema:CreativeWork
291 https://doi.org/10.1039/b314734g schema:sameAs https://app.dimensions.ai/details/publication/pub.1003376524
292 rdf:type schema:CreativeWork
293 https://doi.org/10.1039/b606665h schema:sameAs https://app.dimensions.ai/details/publication/pub.1015308731
294 rdf:type schema:CreativeWork
295 https://doi.org/10.1039/b616847g schema:sameAs https://app.dimensions.ai/details/publication/pub.1010313880
296 rdf:type schema:CreativeWork
297 https://doi.org/10.1039/c39820000286 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048669976
298 rdf:type schema:CreativeWork
299 https://doi.org/10.1039/c39840000949 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002018973
300 rdf:type schema:CreativeWork
301 https://doi.org/10.1039/c39850001280 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043762861
302 rdf:type schema:CreativeWork
303 https://doi.org/10.1039/c39860000540 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034253209
304 rdf:type schema:CreativeWork
305 https://doi.org/10.1039/c39870001829 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029011873
306 rdf:type schema:CreativeWork
307 https://doi.org/10.1039/c39900000053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018675914
308 rdf:type schema:CreativeWork
309 https://doi.org/10.1039/c39920000632 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047198058
310 rdf:type schema:CreativeWork
311 https://doi.org/10.1039/cs9831200099 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009880736
312 rdf:type schema:CreativeWork
313 https://doi.org/10.1039/dt9840000863 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035235465
314 rdf:type schema:CreativeWork
315 https://doi.org/10.1039/dt9930000827 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014315084
316 rdf:type schema:CreativeWork
317 https://doi.org/10.1039/dt9930001671 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041264097
318 rdf:type schema:CreativeWork
319 https://doi.org/10.1039/dt9960002395 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026897814
320 rdf:type schema:CreativeWork
321 https://doi.org/10.1039/jr9620001490 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014599984
322 rdf:type schema:CreativeWork
323 https://doi.org/10.1063/1.464913 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042899913
324 rdf:type schema:CreativeWork
325 https://doi.org/10.1071/ch9851301 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023677982
326 rdf:type schema:CreativeWork
327 https://doi.org/10.1103/physrevb.37.785 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060546104
328 rdf:type schema:CreativeWork
329 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
330 rdf:type schema:CreativeWork
331 https://doi.org/10.1139/v02-127 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007754419
332 rdf:type schema:CreativeWork
333 https://doi.org/10.1139/v05-254 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050072626
334 rdf:type schema:CreativeWork
335 https://www.grid.ac/institutes/grid.266869.5 schema:alternateName University of North Texas
336 schema:name Department of Chemistry, University of North Texas, 1155 Union Circle, Box 305070, 76203, Denton, TX, USA
337 rdf:type schema:Organization
338 https://www.grid.ac/institutes/grid.411808.4 schema:alternateName Jahangirnagar University
339 schema:name Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh
340 rdf:type schema:Organization
341 https://www.grid.ac/institutes/grid.83440.3b schema:alternateName University College London
342 schema:name Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh
343 Department of Chemistry, University College London, 20 Gordon Street, WC1H 0AJ, London, UK
344 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...