Two Coordination Modes of Bidentate Aminopyrazine Ligands in Cubane-type Cluster Complex Re4Te4Cl8(C4N3H4)4 · 2DMF View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-03

AUTHORS

Olga A. Efremova, Yuri V. Mironov, Hans-Jürgen Pietzsch, Holger Stephan, Christiane Perrin, Vladimir E. Fedorov

ABSTRACT

A new cubane-type cluster complex Re4Te4Cl4(C4H4N3)4 · 2DMF has been synthesized by reaction of Re4Te4Cl8(TeCl2)4 with 2-aminopyrazine C4H5N3 in DMF. The crystal structure of compound has been solved by X-ray single crystal diffraction method. Crystal data for Re4Te4Cl4(C4N3H4)4 · 2DMF: a = 22.8718(16) Å, b = 8.5936(7) Å, c = 20.5720(17) Å, βo = 106.493(2), V = 3877.1(5) Å3, R1 = 0.0466, Rw(F2) = 0.1191. In the complex bidentate aminopyrazine ligands are coordinated in two different types, namely, two of four aminopyrazine ligands bind to a single rhenium atom, and each of two other ligands is coordinated as bridge between two rhenium atoms. A new cubane-type cluster complex Re4Te4Cl4(C4H4N3)4 · 2DMF with two coordination modes of bidentate aminopyrazine ligands has been synthesized and structurally characterized. More... »

PAGES

77-81

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-008-0219-0

DOI

http://dx.doi.org/10.1007/s10876-008-0219-0

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