Interaction of [Mo6Cl14]2− with H2Se: Selective Preparation of [Mo6SeCl13]3− View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-03

AUTHORS

Pavel A. Abramov, Maxim N. Sokolov, Alexandr V. Virovets, Eugenia V. Peresypkina, Cristian Vicent, Vladimir P. Fedin

ABSTRACT

Reaction of [Mo6(μ3-Cl)8Cl6]2− with H2Se, generated in situ from ZnSe and 4 M HCl under hydrothermal conditions lead to the substitution of one or two bridging chlorides, depending on the reagents ratio. With the Mo6/ZnSe 1:3 molar ratio [Mo6(μ3-SeCl7)Cl6]3− forms selectively in high yield. Further substitution is more hindered, and even at 1:20 cluster-to-selenide molar ratio a mixture of [Mo6(μ3-SeCl7)Cl6]3− and [Mo6(μ3-Se2Cl6)Cl6]4− is formed. The products were characterized by X-ray, Raman spectra and electrospray ionization mass spectrometry. More... »

PAGES

83-92

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-008-0203-8

DOI

http://dx.doi.org/10.1007/s10876-008-0203-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033965983


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