Synthesis and Crystal Structure of Cucurbit[6]uril Adduct of Hydrogen-bonded Cluster Complex [Mo3(μ3-Se)(μ2-O)3(H2O)6Cl3]+ View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-09

AUTHORS

Pavel A. Abramov, Maxim N. Sokolov, Alexander V. Virovets, Eugenia V. Peresypkina, Vladimir P. Fedin

ABSTRACT

Reaction of [MoOCl5]2− with in situ generated H2Se under hydrothermal conditions (4M HCl, 140 °C) leads to reduction of Mo(V) to Mo(IV) with the formation of a triangular cluster Mo3(μ3-Se)(μ-O)34+ in high yield. It is present in HCl solutions as aqua chlorocomplex [Mo3(μ3-Se)(μ-O)3(H2O)6Cl3]+ which was isolated and structurally characterized as supramolecular adduct with cucurbit[6]uril (CB[6]), {[Mo3(μ3-Se)(μ-O)3(H2O)6Cl3]2CB[6]}Cl2·15H2O. More... »

PAGES

597-605

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-007-0120-2

DOI

http://dx.doi.org/10.1007/s10876-007-0120-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037054907


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