Cluster Oxalate Complexes [W3(μ3-Q)(μ2-Q)3 (C2O4)3(H2O)3]2− (Q=S, Se): Mechanochemical Synthesis and Crystal Structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-09

AUTHORS

Maxim N. Sokolov, Artyom L. Gushchin, Dmitrii Yu. Naumov, Olga A. Gerasko, Vladimir P. Fedin

ABSTRACT

Mechanochemical reaction of cluster coordination polymers (Q=S, Se) with solid leads to the cluster core excision with the formation of anionic complexes . Extraction of the reaction mixture with water followed by crystallization gives crystalline (main product) and (1) (minor product). In the case of the Se cluster, the complex could not be isolated, and the treatment of the aqueous extract with PPh3 gave (2) in a low yield. Alternatively, it was obtained from and in high yield. Both 1 and 2 were characterized by X-ray structure analysis. More... »

PAGES

309-318

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-005-0026-9

DOI

http://dx.doi.org/10.1007/s10876-005-0026-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043726059


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