Unusual Polymers Containing Alternating s and d Elements Connected by Bridging Pivalate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-09

AUTHORS

Elena Fursova, Olga Kuznetsova, Galina Romanenko, Yuri Schvedenkov, Victor Ovcharenko

ABSTRACT

From tetrahydrofurane solutions containing Cu(II) or Co(II) and potassium pivalate (KPiv) (molar ratios Cu/K=1/10, Co/K=1/5) one can isolate polynuclear [K3Co2Piv7(THF)3] (1) and [K6Cu2Piv10(HPiv)(THF)(H2O)2] 2THF (2), respectively. In the solid state the structures of the compounds consist of alternating, oppositely winding helices with a step of 46.085 Å for 1 and 25.260 Å for 2. In 2, the bridging pivalates link the infinite helices into layers. For both compounds, an important peculiarity of the structure is wide separation of transition metal ions (at least 5.327 Å for 1 and 6.791 Å for 2). Due to the presence of excess KPiv in the reaction system, the Cu(II) and Co(II) ions do not “coalesce” into polynuclear complexes typically observed in transition metal pivalates; instead they form unusual polymer systems containing alternating atoms of s and d elements. For transition metal pivalates, this type of structure was found for the first time. More... »

PAGES

319-329

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10876-005-0002-4

DOI

http://dx.doi.org/10.1007/s10876-005-0002-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017560423


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