Experimental study of the heterogeneous reactivity between atomic chlorine and palmitic acid films View Full Text


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Article Info

DATE

2013-12

AUTHORS

Raluca Ciuraru, Michael Ward, Maxence Mendez, Sylvie Gosselin, Nicolas Visez, Denis Petitprez

ABSTRACT

The present study focuses on the heterogeneous reaction between gaseous atomic chlorine and solid palmitic acid films, used as a proxy of the fatty acids detected in atmospheric airborne particles. This reaction is investigated in a coated wall flow tube reactor coupled to a molecular beam mass spectrometer. The reactive surfaces were prepared by coating the inner surface of the reactor. The initial Cl˙ and Cl2 uptake coefficient measured for these heterogeneous reactions is found to be fast: γoCl = 0.07. The rapid formation of hydrogen chloride corresponding with the disappearance of atomic chlorine is highlighted. Furthermore, the formation of new chlorinated species on the solid substrate has been detected by TOF SIMS analysis leading to an ageing process of the surface. A heterogeneous recombination of Cl atoms to Cl2 molecules was observed for aged surfaces. More... »

PAGES

341-355

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10874-013-9271-8

DOI

http://dx.doi.org/10.1007/s10874-013-9271-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031084122


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Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

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