The Crystal Structure and Magnetic Susceptibility of Tetrakis-(μ2-phenylacetato-O,O′)-bis(caprolactam-O)copper(II) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-02

AUTHORS

Kraig A. Wheeler, Mark H. Shroyer, Edward J. Dale, Travis Helgren, Thomas W. Clayton

ABSTRACT

Tetrakis-(μ2-phenylacetato-O,O′)-bis(caprolactam-O)copper(II) (1) was synthesized and characterized by X-ray crystallography, magnetic susceptibility and FT-IR spectroscopy. The title compound (1) crystallized in the monoclinic space group P21/n with unit cell parameters a = 18.2242(4) Å, b = 10.0994(2) Å, c = 23.0696(5) Å, β = 101.117(2)°; V = 4166.37(15) Å3; Z = 4. The molecular structure of (1) consists of a copper dimer bridged by four phenylacetate ligands in the paddlewheel geometry with caprolactam coordinated in both axial sites. The copper dimers of (1) are organized into one-dimensional columns by N–H···O interactions between bound caprolactam ligands. Magnetic susceptibility studies indicate antiferromagnetic coupling between the Cu+2 ions with a singlet ground-state and triplet excited-state separated by |2J = 319(1) cm−1|. Tetrakis-(μ2-phenylacetato-O,O′)-bis(caprolactam-O)copper(II) (1) was synthesized and characterized by X-ray crystallography, magnetic susceptibility and FT-IR spectroscopy producing paddlewheel copper dimers of (1) organized into columns by N–H···O interactions between bound caprolactam ligands. More... »

PAGES

130-135

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10870-011-0213-5

DOI

http://dx.doi.org/10.1007/s10870-011-0213-5

DIMENSIONS

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