Resolution of 1,1′-Binaphthyl-2,2′-Dicarboxylic Acid with Quinine: Structure of the Intermediate (S)-1,1′-Binaphthyl-2,2′-Dicarboxylate Dihydrate Diastereomeric Salt View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-06

AUTHORS

Ayesha Jacobs, Luigi R. Nassimbeni, Amina Sayed, Edwin Weber

ABSTRACT

Racemic 1,1′-binaphthyl-2,2′-dicarboxylic acid (BNDA) was resolved using quinine as the resolving agent. The structure of the resultant quininium (S)-1,1′-binaphthyl-2,2′-dicarboxylate dihydrate salt (1) was elucidated. The asymmetric unit contained one 1,1′-binaphthyl-2,2′-dicarboxylate anion, two quininium cations and two water molecules. The structure was solved successfully in the orthorhombic space group P212121 with unit cell dimensions: a = 11.100(2) Å, b = 16.572(3) Å, c = 28.726(6) Å. Racemic 1,1′-binaphthyl-2,2′-dicarboxylic acid (BNDA) was resolved using quinine as the resolving agent. The structure of the resultant quininium (S)-1,1′-binaphthyl-2,2′-dicarboxylate dihydrate salt (1) was elucidated. More... »

PAGES

854-857

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10870-011-0012-z

DOI

http://dx.doi.org/10.1007/s10870-011-0012-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015729165


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