Crystal Structure of a Trinuclear Mercury(II) Cyanide Complex of Tetramethylthiourea, [{(Tetramethylthiourea)2Hg(CN)2}2·Hg(CN)2] View Full Text


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Article Info

DATE

2010-12

AUTHORS

Muhammad Altaf, Helen Stoeckli-Evans, Saeed Ahmad, Anvarhusein A. Isab, Abdul Rahman Al-Arfaj, Muhammad Riaz Malik, Saqib Ali

ABSTRACT

The title compound was prepared by reacting mercury(II) cyanide and tetramethylthiourea (Tmtu) in the molar ratio of 1:1.75. It was characterized by IR and NMR (1H and 13C) spectroscopy, and X-ray crystallography. The appearance of a band around 2,200 cm−1 in IR and a resonance around 145 ppm in 13C NMR indicated the binding of cyanide to mercury(II). The crystal structure of the title complex, [{(tetramethylthiourea)2Hg(CN)2}2·Hg(CN)2] (1) consists of two independent [(Tmtu)2Hg(CN)2] moieties bridged by a Hg(CN)2 unit. The mercury atom in [(Tmtu)2Hg(CN)2] unit is coordinated to two thione sulfur atoms of Tmtu and to two cyanide carbon atoms in a distorted tetrahedral mode. The title compound, [{(tetramethylthiourea)2Hg(CN)2}2·Hg(CN)2] (1) was prepared by reacting mercury(II) cyanide and tetramethylthiourea (Tmtu) in the molar ratio of 1.75:1. It was characterized by IR and NMR (1H and 13C) spectroscopy, and x-ray crystallography. The appearance of a band around 2200 cm−1 in IR and a resonance around 145 ppm in 13C NMR indicated the binding of cyanide to mercury(II). The crystal structure of the complex consists of two independent [(Tmtu)2Hg(CN)2] moieties bridged by a Hg(CN)2 unit. The mercury atom in [(Tmtu)2Hg(CN)2] unit is coordinated to two thione sulfur atoms of Tmtu and to two cyanide carbon atoms in a distorted tetrahedral mode. The title compound, [{(tetramethylthiourea)2Hg(CN)2}2·Hg(CN)2] (1) was prepared by reacting mercury(II) cyanide and tetramethylthiourea (Tmtu) in the molar ratio of 1.75:1. It was characterized by IR and NMR (1H and 13C) spectroscopy, and x-ray crystallography. The appearance of a band around 2200 cm−1 in IR and a resonance around 145 ppm in 13C NMR indicated the binding of cyanide to mercury(II). The crystal structure of the complex consists of two independent [(Tmtu)2Hg(CN)2] moieties bridged by a Hg(CN)2 unit. The mercury atom in [(Tmtu)2Hg(CN)2] unit is coordinated to two thione sulfur atoms of Tmtu and to two cyanide carbon atoms in a distorted tetrahedral mode. More... »

PAGES

1175-1179

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10870-010-9818-3

DOI

http://dx.doi.org/10.1007/s10870-010-9818-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052525521


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