A Six-Connected 3D Europium Coordination Polymer Assembled by 5-Bromoisophthalic Acid (H2BIPA) and 1,10-Phenanthroline (phen): Synthesis, Characterization and Luminescent Property View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-03

AUTHORS

Guang-Xiang Liu, Rong-Yi Huang, Liang-Fang Huang, Heng Xu, Xiao-Ming Ren

ABSTRACT

A novel three-dimensional coordination polymer, [Eu2(phen)2(BIPA)3]·2H2O (1) (BIPA = 5-bromoisophthalate), has been synthsized by the reaction 5-bromoisophthalic acid with Eu(NO3)3·6H2O under the hydrothermal conditions and characterized by IR, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic space group Pī and affords a three-dimensional (3D) six-connected α-Po network. Complex 1 showed the characteristic emission spectra of the EuIII and appeared to have good fluorescence properties. Synthesis, crystal structure and photophysical property of europium coordination polymer assembled by 5-bromoisophthalic acid (H2BIPA) and 1,10-phenanthroline (phen) A novel three-dimensional coordination polymer, [Eu2(phen)2(BIPA)3]·2H2O (1) (BIPA = 5-bromoisophthalate), has been synthsized by the reaction 5-bromoisophthalic acid with Eu(NO3)3·6H2O under the hydrothermal conditions and characterized by IR, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic space group Pī and affords a three-dimensional (3D) six-connected α-Po network. The photophysical property of 1 was investigated. More... »

PAGES

283-287

References to SciGraph publications

  • 1994. Luminescent Materials in NONE
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