The Crystal Structure of dl-Lomenfloxacin Hydrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-05

AUTHORS

Zhan Shu, Hai Yan Li, Lin Lin Ma, Wei Liang Chen, Zhi Min Jin

ABSTRACT

The dl-lomenfloxacin hydrate is an innersalt, which crystallizes in space group C2/c with cell parameters a = 22.897(10), b = 8.682(1), c = 18.365(2) Å, β = 93.633(9)°, V = 3,705(3) Å3 and Z = 8. The piperazinyl ring adopts a chair conformation, and the quinolone ring is essentially planar. The plane defined by C atoms of the piperazinyl ring is not coplanar with the quinolone ring. The carboxylate group shows two disorder parts, and is not coplanar with the quinolone ring, the dihedral angle between them is 113.8°. The disorder carboxylate group is split into two parts, the planes of which are skewed at the dihedral angles of 24.5 and 21.6° with the plane of the quinolone ring, respectively. The IR of the title compound is measured and studied. The crystal structure of dl-lomenfloxacin hydrate is determined by X-ray diffraction. The IR is measured and shows great differences from previous studies. More... »

PAGES

384-388

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10870-009-9531-2

DOI

http://dx.doi.org/10.1007/s10870-009-9531-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042876279


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