Synthesis, spectroscopic characterization and X-ray structure determination of tetrabutylammonium trans-diamminetetranitrocobaltate(III) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-10

AUTHORS

Raj Pal Sharma, Rajni Sharma, Ritu Bala, Dip Singh Gill, Sukhjinder Singh, Jugal Kishor Puri, Luca Russo, Kari Rissanen

ABSTRACT

The cobalt(III) complex salt [(C4H9)4N][trans-Co(NH3)2(NO2)4] has been synthesized in high yield by reacting equimolar quantities of [(C4H9)4N]Br and K[trans-Co(NH3)2(NO2)4] in aqueous medium at room temperature. The product thus formed has been re-crystallised from acetone-water mixture, in the monoclinic space group P 21/n, with cell dimensions a=11.651(3) Å, b=19.005(4) Å, c=11.733(5) Å, β=90.28(3)°. The X-ray structure determination revealed the presence of discrete ions, [(C4H9)4N]+ and [trans-Co(NH3)2(NO2)4]−. The central metal ion cobalt(III) in the anion is found in octahedral environment, in trans geometry, while the organic counterion is a quaternary alkylammonium cation. The crystal lattice is stabilized by electrostatic interactions between the cations and anions. More... »

PAGES

619-625

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10870-006-9106-4

DOI

http://dx.doi.org/10.1007/s10870-006-9106-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039940140


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Download the RDF metadata as:  json-ld nt turtle xml License info

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Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10870-006-9106-4'


 

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