Peculiarities in thermal evolution of precipitated amorphous calcium phosphates with an initial Ca/P ratio of 1:1 View Full Text


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Article Info

DATE

2017-02-14

AUTHORS

Zoltan Zyman, Matthias Epple, Anton Goncharenko, Dmytro Rokhmistrov, Oleg Prymak, Kateryna Loza

ABSTRACT

Thermal evolution of amorphous calcium phosphate (ACP) powder from a fast nitrate synthesis with a Ca/P ratio of 1:1 were studied in the range of 20–980 °C. The powder consisted of amorphous dicalcium phosphate anhydrate (CaHPO4) after heating to 200 °C. CaHPO4 gradually condensed to amorphous calcium pyrophosphate Ca2P2O7 (CPP) between 200 to 620 °C. Amorphous CPP crystallized at 620–740 °C to a metastable polymorph α′-CPP of the high-temperature phase α-CPP and β-CPP. The α′-CPP/ β-CPP phase ratio reached a maximum at 800 °C (60 wt% α′-CPP/40 wt% β-CPP), and α′-CPP gradually transformed to β-CPP at a higher temperature. Some β-TCP occurred at 900 °C, so that a three-phasic mixture was obtained in the powder heated to 980 °C. The occurrence of metastable α′-CPP is attributed to Ostwald’s step rule, and a mechanism for β-TCP formation is proposed. The advantages of prospective biomaterials from these powders are discussed. More... »

PAGES

52

References to SciGraph publications

  • 2009-03-10. Thermal impurity reactions and structural changes in slightly carbonated hydroxyapatite in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • 2003-03. Biphasic calcium phosphate bioceramics: preparation, properties and applications in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • 2004-04. Influence of Ca/P ratios of starting solutions on the crystallization of amorphous calcium phosphate to hydroxyapatite in METALS AND MATERIALS INTERNATIONAL
  • 2014-05-28. Bone substitutes in orthopaedic surgery: from basic science to clinical practice in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • 2007-06-12. In vitro synthesis and characterization of amorphous calcium phosphates with various Ca/P atomic ratios in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • 2009-09-16. Structural and compositional features of amorphous calcium phosphate at the early stage of precipitation in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • 2004-05. Nonstoichiometric hydroxyapatite granules for orthopaedic applications in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN MEDICINE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10856-016-5820-4

    DOI

    http://dx.doi.org/10.1007/s10856-016-5820-4

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1083831143

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/28197825


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