Preparation and electrochemical properties of nanoparticle structural LiFePO4/C by Sol–Gel method as cathode material for lithium ion batteries View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-02-22

AUTHORS

Zongfeng Li, Guixia Dong, Jingrui Kang, Lei Li

ABSTRACT

In this study, LiFePO4/C nanocomposites with higher capacity and cycle performance are synthesized by sol–gel method using FeCl2·4H2O, H3PO4, Li2CO3, and Citric acid as the starting materials. LiFePO4/C cathode materials with different grain size and electrochemical properties were obtained by changing the calcination temperature of LiFePO4/C precursor prepared by sol–gel method. Specially, the LiFePO4/C precursor prepared by sol–gel method was heated to 700 °C for 12 h under nitrogen atmosphere, and the nanoparticle structural LiFePO4/C was obtained. The first discharge specific capacity is 156.5 mAh g−1 at a charging current of 0.2 C. The first discharge specific capacity is 124.5 mAh g−1 at a charging current of 1 C, and after the 250th cycles, the discharge specific capacity is 120.7 mAh g−1, the retention rate of discharge specific capacity is 96.9%. More... »

PAGES

1-8

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10854-019-00966-1

DOI

http://dx.doi.org/10.1007/s10854-019-00966-1

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https://app.dimensions.ai/details/publication/pub.1112305431


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