Fabrication and enhancement in photoconductive response of α-Fe2O3/graphene nanocomposites as anode material View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-08-21

AUTHORS

Naveed Alam, Arif Ullah, Yaqoob Khan, Won Chun Oh, Kefayat Ullah

ABSTRACT

We report a facile fabrication for the synthesis of graphene based α-Fe2O3 nanocomposites as anode material for photoelectrochemical water splitting. The effect of introduction of graphene as a solid-state electron material has been investigated in detail by controlling the synthesis parameters. The XRD pattern of hematite α-Fe2O3 nanoparticles were indexed to rhombohedral structure of α-Fe2O3, while the TEM images illustrate the flaky structure of graphene supported by hematite nanoparticles. The rGO/α\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\alpha$$\end{document}-Fe2O3 nanocomposites showed enhanced photocurrent of ~ 4 mA cm−2 at (1.23 V vs. RHE) under standard illumination conditions (AM 1.5 G 100 mW cm−2). The enhanced photoelectrochemical performance may be attributed to synergistic effect of graphene and α\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\alpha$$\end{document}-Fe2O3 by improving the charge transport properties. The optical properties were also observed to be influenced by the coupling of rGO and α-Fe2O3 composites as witnessed in the DRS spectra. More... »

PAGES

17786-17794

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10854-018-9886-2

DOI

http://dx.doi.org/10.1007/s10854-018-9886-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106277044


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