Synthesis of polyfluorenes by oxidative polymerization, their characterization and implementation in organic solar cells View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-02

AUTHORS

Arián Espinosa-Roa, María de Jesús Cruz-Carrillo, Arelis Ledesma-Juárez, Alejandra Montoya del Angel, Daniel Romero-Borja, Marisol Güizado-Rodríguez, Mario Rodríguez, Rosario Galindo, José Luis Maldonado, Victor Barba

ABSTRACT

Polyfluorene materials have demonstrated to be important components in the fabrication of organic solar cell devices, in both: the active and electron transport layers. The oxidative synthesis as well as optical and electrical properties of new polyfluorene copolymers containing 2,2′-(9,9-dioctyl-9H-fluorene-2,7-diyl) bistiophene and 3-alkylthiophene, alkyl = hexyl (PA1) and octyl (PA2) or 3,4-ethylenedioxythiophene (EDOT) (PM) were investigated. Changes in the HOMO–LUMO energy gap promoted for the insertion of EDOT ring were studied in thick film by using cyclic-voltammetry measurements and compared with the optical properties analyzed by UV–Visible spectroscopy. DFT calculations were used to investigate the possible electronic density distribution and conformational parameter for repetition units into the polymeric structure. Finally, these polymer were preliminary evaluated as donor materials into organic solar cells with architecture ITO/PEDOT:PSS/co-polymer:PC71BM/Field’s metal. Photovoltaic devices showed a very acceptable open circuit voltage (Voc) value, up to 0.92 V. More... »

PAGES

2716-2725

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1007/s10854-018-0547-2

DOI

http://dx.doi.org/10.1007/s10854-018-0547-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110668406


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10854-018-0547-2'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10854-018-0547-2'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10854-018-0547-2'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10854-018-0547-2'


 

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