Molten salt synthesis and tunable photoluminescent properties of Eu3+–Tb3+ doped NaY(MoO4)2 microcrystals View Full Text


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Article Info

DATE

2015-05

AUTHORS

Xue Zhang, Yunfei Liu, Yinong Lu, Bingyan Li, Fei Song, Fengling Yang

ABSTRACT

Octahedron-like and rod-like NaY(MoO4)2 microcrystals with tetragonal scheelite-type structure were successfully synthesized by a low cost molten salt method using NaCl as the reaction medium. The as-obtained products were characterized by powder X-ray diffractometer, thermal field emission scanning electron microscope, and photoluminescence spectrometer. The results show that NaY(MoO4)2 with different morphologies have been controllably obtained via adjusting calcining temperature and reaction time. Under the UV light excitation, the emission intensity of the octahedron-like NaY(MoO4)2:Eu3+/Tb3+ microcrystals is stronger than the rod-like ones. Moreover, the luminescence colors of the Eu3+–Tb3+ co-doped NaY(MoO4)2 octahedron-like microcrystals can be tuned from red, orange, yellow and green-yellow to green by simply adjusting the relative doping concentrations of the activator ions, which might have potential application in the areas such as optoelectronic devices in the future. More... »

PAGES

2987-2994

References to SciGraph publications

  • 2013-01. Controlled synthesis, formation mechanism and lumincence properties of novel 3-dimensional Gd2(MoO4)3:Eu3+ nanostructures in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS
  • 2014-08. Morphology and photoluminescence properties of KSm(MoO4)2 microcrystals by a molten salt method in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS
  • 2013-12. Influence of Eu3+ ions in Na0.5La0.5MoO4: structural and optical investigation in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS
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