Function of glycine during solid-state reaction toward well-crystallized fine particulate barium titanate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-10-14

AUTHORS

Chie Ando, Koichiro Tsuzuku, Tomomi Kobayashi, Hiroshi Kishi, Shinichi Kuroda, Mamoru Senna

ABSTRACT

Effects of glycine added to BaCO3 and TiO2 mixtures were examined during a solid-state reaction toward phase pure BaTiO3 for MLCC with the average particle size below 180 nm and the tetragonality, c/a, above 1.009. Changes in the states of glycine during heating were monitored by differential thermogravimetry and high-temperature X-ray photoelectron spectroscopy. Glycine residue persists up to around 350 °C and destabilizes Ti–O bonds in TiO2 prior to the initiation of reaction toward BaTiO3. This, in turn, leads to a decrease in the reaction termination temperature due to higher mobility of Ba2+ ions through the reaction zone. More... »

PAGES

844

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10854-008-9804-0

DOI

http://dx.doi.org/10.1007/s10854-008-9804-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027439115


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