Verwey transition temperature distribution in magnetic nanocomposites containing polydisperse magnetite nanoparticles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-06

AUTHORS

G. Barrera, P. Tiberto, C. Sciancalepore, M. Messori, F. Bondioli, P. Allia

ABSTRACT

Polymeric nanocomposites containing Fe3O4 nanoparticles were prepared through a chemical route under different precursor-to-solvent ratios and were submitted to structural and morphologic characterization. The embedded nanoparticles, containing pure magnetite and characterized by considerable polydispersity, are rather homogeneously dispersed in the matrix. The magnetic properties of two representative samples were analyzed in detail between T = 5 K and room temperature. Magnetic effects clearly associated with the Verwey monoclinic to cubic transition with transition temperatures distributed in the interval 95–120 K were put in evidence. On heating through this region, the coercive field and the maximum susceptibility of hysteresis loops display marked downward/upward steps, respectively, while the high-field magnetization is not affected at all; a comparable upward step is measured in the FC/ZFC curves. Reporting the maximum susceptibility as a function of the reciprocal of the coercive field in the interval from T = 95 to T = 120 K, and using the predictions for single-domain nanoparticles with randomly distributed axes of uniaxial and cubic anisotropy (the former/latter case being applicable below/above the Verwey transition, respectively), the evolution of the transformed cubic-anisotropy fraction upon heating has been studied, and the distribution of Verwey transition temperatures related to the sample polydispersity has been accurately determined. The low-temperature value of the uniaxial anisotropy constant is obtained from coercive field measurements and found to be comparable to, albeit slightly higher than the corresponding quantity measured in bulk crystalline magnetite. More... »

PAGES

8346-8360

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10853-019-03510-y

DOI

http://dx.doi.org/10.1007/s10853-019-03510-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112634196


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Istituto Nazionale di Ricerca Metrologica", 
          "id": "https://www.grid.ac/institutes/grid.425358.d", 
          "name": [
            "Advanced Materials for Metrology and Life Sciences, INRiM, Strada delle Cacce 91, 10135, Turin, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Barrera", 
        "givenName": "G.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Istituto Nazionale di Ricerca Metrologica", 
          "id": "https://www.grid.ac/institutes/grid.425358.d", 
          "name": [
            "Advanced Materials for Metrology and Life Sciences, INRiM, Strada delle Cacce 91, 10135, Turin, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tiberto", 
        "givenName": "P.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Interuniversity Consortium of Materials Science and Technology", 
          "id": "https://www.grid.ac/institutes/grid.182470.8", 
          "name": [
            "National Interuniversity Consortium of Materials Science and Technology, INSTM, Via Giusti 9, 50121, Florence, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sciancalepore", 
        "givenName": "C.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Department of Engineering \u201cEnzo Ferrari\u201d, University of Modena and Reggio, Via Vivarelli 10, 41125, Modena, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Messori", 
        "givenName": "M.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Polytechnic University of Turin", 
          "id": "https://www.grid.ac/institutes/grid.4800.c", 
          "name": [
            "National Interuniversity Consortium of Materials Science and Technology, INSTM, Via Giusti 9, 50121, Florence, Italy", 
            "DISAT, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129, Turin, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bondioli", 
        "givenName": "F.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Polytechnic University of Turin", 
          "id": "https://www.grid.ac/institutes/grid.4800.c", 
          "name": [
            "DISAT, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129, Turin, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Allia", 
        "givenName": "P.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.3390/gels1010024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002423118"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/gels1010024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002423118"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/gels1010024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002423118"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jallcom.2009.11.119", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004649239"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchemphys.2014.07.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004886528"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/macp.201200494", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004900275"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/16/7/r01", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005548196"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11051-011-0715-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018504952", 
          "https://doi.org/10.1007/s11051-011-0715-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/srep20897", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021571155", 
          "https://doi.org/10.1038/srep20897"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0378-4363(77)90759-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021838589"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0378-4363(77)90759-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021838589"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1024339857", 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-84882-671-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024339857", 
          "https://doi.org/10.1007/978-1-84882-671-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-84882-671-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024339857", 
          "https://doi.org/10.1007/978-1-84882-671-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.snb.2013.07.091", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024635395"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1029/gl011i003p00185", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026898978"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cplett.2004.04.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031489988"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10971-016-4095-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032743230", 
          "https://doi.org/10.1007/s10971-016-4095-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10971-016-4095-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032743230", 
          "https://doi.org/10.1007/s10971-016-4095-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2014.12.047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033291389"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0032-5910(03)00048-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033916773"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(83)90698-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035886310"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(83)90698-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035886310"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0380852", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038558732"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0380852", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038558732"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/14/12/203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039498413"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1046/j.1365-246x.2000.00081.x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041676207"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchar.2014.12.013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042078475"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0022-3727/40/19/001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042131266"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1155/2016/7840161", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043052062"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.partic.2016.06.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043261891"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0012-821x(79)90168-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044015899"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0012-821x(79)90168-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044015899"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0304-8853(97)00180-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045946334"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jmmm.2012.04.049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047517263"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0022-3727/36/13/202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049456758"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-016-0380-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050224107", 
          "https://doi.org/10.1007/s10853-016-0380-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-016-0380-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050224107", 
          "https://doi.org/10.1007/s10853-016-0380-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/s8095775", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052207153"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.jpclett.6b00644", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055114366"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.nanolett.5b00331", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055120589"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm050060+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411293"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm050060+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411293"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp501652e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056100010"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1599959", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057724483"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1853931", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057828254"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2172891", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057842594"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.4797628", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058072955"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.40.9090", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060552724"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.40.9090", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060552724"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.43.8461", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060558164"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.43.8461", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060558164"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.74.064425", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060618429"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.74.064425", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060618429"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/tmag.1979.1060319", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1061669466"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1143/jpsj.41.1894", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1063102461"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1557/proc-746-q4.1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067955157"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1166/jnn.2008.15348", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1077684958"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.msec.2017.04.066", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084924837"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2017.07.022", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090741766"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-017-1923-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100078551", 
          "https://doi.org/10.1007/s10853-017-1923-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchemphys.2017.12.089", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100108903"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-018-2684-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1105642820", 
          "https://doi.org/10.1007/s10853-018-2684-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-018-2684-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1105642820", 
          "https://doi.org/10.1007/s10853-018-2684-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-018-2899-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1106984316", 
          "https://doi.org/10.1007/s10853-018-2899-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.98.134423", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1107639104"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.98.134423", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1107639104"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-06", 
    "datePublishedReg": "2019-06-01", 
    "description": "Polymeric nanocomposites containing Fe3O4 nanoparticles were prepared through a chemical route under different precursor-to-solvent ratios and were submitted to structural and morphologic characterization. The embedded nanoparticles, containing pure magnetite and characterized by considerable polydispersity, are rather homogeneously dispersed in the matrix. The magnetic properties of two representative samples were analyzed in detail between T = 5 K and room temperature. Magnetic effects clearly associated with the Verwey monoclinic to cubic transition with transition temperatures distributed in the interval 95\u2013120 K were put in evidence. On heating through this region, the coercive field and the maximum susceptibility of hysteresis loops display marked downward/upward steps, respectively, while the high-field magnetization is not affected at all; a comparable upward step is measured in the FC/ZFC curves. Reporting the maximum susceptibility as a function of the reciprocal of the coercive field in the interval from T = 95 to T = 120 K, and using the predictions for single-domain nanoparticles with randomly distributed axes of uniaxial and cubic anisotropy (the former/latter case being applicable below/above the Verwey transition, respectively), the evolution of the transformed cubic-anisotropy fraction upon heating has been studied, and the distribution of Verwey transition temperatures related to the sample polydispersity has been accurately determined. The low-temperature value of the uniaxial anisotropy constant is obtained from coercive field measurements and found to be comparable to, albeit slightly higher than the corresponding quantity measured in bulk crystalline magnetite.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10853-019-03510-y", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312116", 
        "issn": [
          "0022-2461", 
          "1573-4811"
        ], 
        "name": "Journal of Materials Science", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "54"
      }
    ], 
    "name": "Verwey transition temperature distribution in magnetic nanocomposites containing polydisperse magnetite nanoparticles", 
    "pagination": "8346-8360", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "ddb63f46d3b965a2adeb676e32676cb5b14e9d32f267e8686aee9ec43d9396ab"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10853-019-03510-y"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112634196"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10853-019-03510-y", 
      "https://app.dimensions.ai/details/publication/pub.1112634196"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000361_0000000361/records_54002_00000002.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs10853-019-03510-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10853-019-03510-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10853-019-03510-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10853-019-03510-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10853-019-03510-y'


 

This table displays all metadata directly associated to this object as RDF triples.

262 TRIPLES      21 PREDICATES      79 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10853-019-03510-y schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N3fcd78baecfd4c26956cc6e89d19e50a
4 schema:citation sg:pub.10.1007/978-1-84882-671-7
5 sg:pub.10.1007/s10853-016-0380-z
6 sg:pub.10.1007/s10853-017-1923-7
7 sg:pub.10.1007/s10853-018-2684-7
8 sg:pub.10.1007/s10853-018-2899-7
9 sg:pub.10.1007/s10971-016-4095-z
10 sg:pub.10.1007/s11051-011-0715-2
11 sg:pub.10.1038/srep20897
12 https://app.dimensions.ai/details/publication/pub.1024339857
13 https://doi.org/10.1002/macp.201200494
14 https://doi.org/10.1016/0012-821x(79)90168-7
15 https://doi.org/10.1016/0304-8853(83)90698-4
16 https://doi.org/10.1016/0378-4363(77)90759-8
17 https://doi.org/10.1016/j.cplett.2004.04.005
18 https://doi.org/10.1016/j.eurpolymj.2017.07.022
19 https://doi.org/10.1016/j.jallcom.2009.11.119
20 https://doi.org/10.1016/j.jmmm.2012.04.049
21 https://doi.org/10.1016/j.matchar.2014.12.013
22 https://doi.org/10.1016/j.matchemphys.2014.07.020
23 https://doi.org/10.1016/j.matchemphys.2017.12.089
24 https://doi.org/10.1016/j.msec.2017.04.066
25 https://doi.org/10.1016/j.partic.2016.06.001
26 https://doi.org/10.1016/j.polymer.2014.12.047
27 https://doi.org/10.1016/j.snb.2013.07.091
28 https://doi.org/10.1016/s0032-5910(03)00048-2
29 https://doi.org/10.1016/s0304-8853(97)00180-7
30 https://doi.org/10.1021/acs.jpclett.6b00644
31 https://doi.org/10.1021/acs.nanolett.5b00331
32 https://doi.org/10.1021/cm050060+
33 https://doi.org/10.1021/ja0380852
34 https://doi.org/10.1021/jp501652e
35 https://doi.org/10.1029/gl011i003p00185
36 https://doi.org/10.1046/j.1365-246x.2000.00081.x
37 https://doi.org/10.1063/1.1599959
38 https://doi.org/10.1063/1.1853931
39 https://doi.org/10.1063/1.2172891
40 https://doi.org/10.1063/1.4797628
41 https://doi.org/10.1088/0022-3727/36/13/202
42 https://doi.org/10.1088/0022-3727/40/19/001
43 https://doi.org/10.1088/0953-8984/14/12/203
44 https://doi.org/10.1088/0953-8984/16/7/r01
45 https://doi.org/10.1103/physrevb.40.9090
46 https://doi.org/10.1103/physrevb.43.8461
47 https://doi.org/10.1103/physrevb.74.064425
48 https://doi.org/10.1103/physrevb.98.134423
49 https://doi.org/10.1109/tmag.1979.1060319
50 https://doi.org/10.1143/jpsj.41.1894
51 https://doi.org/10.1155/2016/7840161
52 https://doi.org/10.1166/jnn.2008.15348
53 https://doi.org/10.1557/proc-746-q4.1
54 https://doi.org/10.3390/gels1010024
55 https://doi.org/10.3390/s8095775
56 schema:datePublished 2019-06
57 schema:datePublishedReg 2019-06-01
58 schema:description Polymeric nanocomposites containing Fe3O4 nanoparticles were prepared through a chemical route under different precursor-to-solvent ratios and were submitted to structural and morphologic characterization. The embedded nanoparticles, containing pure magnetite and characterized by considerable polydispersity, are rather homogeneously dispersed in the matrix. The magnetic properties of two representative samples were analyzed in detail between T = 5 K and room temperature. Magnetic effects clearly associated with the Verwey monoclinic to cubic transition with transition temperatures distributed in the interval 95–120 K were put in evidence. On heating through this region, the coercive field and the maximum susceptibility of hysteresis loops display marked downward/upward steps, respectively, while the high-field magnetization is not affected at all; a comparable upward step is measured in the FC/ZFC curves. Reporting the maximum susceptibility as a function of the reciprocal of the coercive field in the interval from T = 95 to T = 120 K, and using the predictions for single-domain nanoparticles with randomly distributed axes of uniaxial and cubic anisotropy (the former/latter case being applicable below/above the Verwey transition, respectively), the evolution of the transformed cubic-anisotropy fraction upon heating has been studied, and the distribution of Verwey transition temperatures related to the sample polydispersity has been accurately determined. The low-temperature value of the uniaxial anisotropy constant is obtained from coercive field measurements and found to be comparable to, albeit slightly higher than the corresponding quantity measured in bulk crystalline magnetite.
59 schema:genre research_article
60 schema:inLanguage en
61 schema:isAccessibleForFree false
62 schema:isPartOf N699480e21a454e0897280347c6d2fa5c
63 Nf0219ad5d4424856b143956a0af81d76
64 sg:journal.1312116
65 schema:name Verwey transition temperature distribution in magnetic nanocomposites containing polydisperse magnetite nanoparticles
66 schema:pagination 8346-8360
67 schema:productId N117dd7b38c1f40409b3cf1f3e22564ce
68 N330f65a5ff414c30a097905557fa1ae0
69 Nc3293df7858f48ad9595c96542634c40
70 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112634196
71 https://doi.org/10.1007/s10853-019-03510-y
72 schema:sdDatePublished 2019-04-11T12:14
73 schema:sdLicense https://scigraph.springernature.com/explorer/license/
74 schema:sdPublisher N74bcdeed420e4ccca78aad438cf06ab0
75 schema:url https://link.springer.com/10.1007%2Fs10853-019-03510-y
76 sgo:license sg:explorer/license/
77 sgo:sdDataset articles
78 rdf:type schema:ScholarlyArticle
79 N117dd7b38c1f40409b3cf1f3e22564ce schema:name readcube_id
80 schema:value ddb63f46d3b965a2adeb676e32676cb5b14e9d32f267e8686aee9ec43d9396ab
81 rdf:type schema:PropertyValue
82 N330f65a5ff414c30a097905557fa1ae0 schema:name dimensions_id
83 schema:value pub.1112634196
84 rdf:type schema:PropertyValue
85 N3fcd78baecfd4c26956cc6e89d19e50a rdf:first N55a0bdcdd84f4e4fad5fff803ca7811f
86 rdf:rest N40748e7a3c3f4cd4835a6aa565aa7ef4
87 N40748e7a3c3f4cd4835a6aa565aa7ef4 rdf:first N7e96d27d853f495c94b84594d089ea09
88 rdf:rest N90987c2076b3466ab3331a655b8db071
89 N55a0bdcdd84f4e4fad5fff803ca7811f schema:affiliation https://www.grid.ac/institutes/grid.425358.d
90 schema:familyName Barrera
91 schema:givenName G.
92 rdf:type schema:Person
93 N5adc7fa0979042e7b712125b3b843aea schema:affiliation https://www.grid.ac/institutes/grid.4800.c
94 schema:familyName Bondioli
95 schema:givenName F.
96 rdf:type schema:Person
97 N699480e21a454e0897280347c6d2fa5c schema:volumeNumber 54
98 rdf:type schema:PublicationVolume
99 N74bcdeed420e4ccca78aad438cf06ab0 schema:name Springer Nature - SN SciGraph project
100 rdf:type schema:Organization
101 N77d0e037b4334fb88683758e639e86af rdf:first Ndeff312c5b544290b7ea97883f2a4521
102 rdf:rest rdf:nil
103 N7c268ee5bea84078967f20d3fc895935 schema:name Department of Engineering “Enzo Ferrari”, University of Modena and Reggio, Via Vivarelli 10, 41125, Modena, Italy
104 rdf:type schema:Organization
105 N7e96d27d853f495c94b84594d089ea09 schema:affiliation https://www.grid.ac/institutes/grid.425358.d
106 schema:familyName Tiberto
107 schema:givenName P.
108 rdf:type schema:Person
109 N90987c2076b3466ab3331a655b8db071 rdf:first Na2047cd2a9a74d87ba3bc70127568061
110 rdf:rest Naa4c4706779b4f9988300276c9a53176
111 Na2047cd2a9a74d87ba3bc70127568061 schema:affiliation https://www.grid.ac/institutes/grid.182470.8
112 schema:familyName Sciancalepore
113 schema:givenName C.
114 rdf:type schema:Person
115 Naa4c4706779b4f9988300276c9a53176 rdf:first Nc7407f59645644fe8deef6fe02dec70d
116 rdf:rest Nce73440a98554d2f93ed5ef1b747cf3f
117 Nc3293df7858f48ad9595c96542634c40 schema:name doi
118 schema:value 10.1007/s10853-019-03510-y
119 rdf:type schema:PropertyValue
120 Nc7407f59645644fe8deef6fe02dec70d schema:affiliation N7c268ee5bea84078967f20d3fc895935
121 schema:familyName Messori
122 schema:givenName M.
123 rdf:type schema:Person
124 Nce73440a98554d2f93ed5ef1b747cf3f rdf:first N5adc7fa0979042e7b712125b3b843aea
125 rdf:rest N77d0e037b4334fb88683758e639e86af
126 Ndeff312c5b544290b7ea97883f2a4521 schema:affiliation https://www.grid.ac/institutes/grid.4800.c
127 schema:familyName Allia
128 schema:givenName P.
129 rdf:type schema:Person
130 Nf0219ad5d4424856b143956a0af81d76 schema:issueNumber 11
131 rdf:type schema:PublicationIssue
132 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
133 schema:name Chemical Sciences
134 rdf:type schema:DefinedTerm
135 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
136 schema:name Physical Chemistry (incl. Structural)
137 rdf:type schema:DefinedTerm
138 sg:journal.1312116 schema:issn 0022-2461
139 1573-4811
140 schema:name Journal of Materials Science
141 rdf:type schema:Periodical
142 sg:pub.10.1007/978-1-84882-671-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024339857
143 https://doi.org/10.1007/978-1-84882-671-7
144 rdf:type schema:CreativeWork
145 sg:pub.10.1007/s10853-016-0380-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1050224107
146 https://doi.org/10.1007/s10853-016-0380-z
147 rdf:type schema:CreativeWork
148 sg:pub.10.1007/s10853-017-1923-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100078551
149 https://doi.org/10.1007/s10853-017-1923-7
150 rdf:type schema:CreativeWork
151 sg:pub.10.1007/s10853-018-2684-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1105642820
152 https://doi.org/10.1007/s10853-018-2684-7
153 rdf:type schema:CreativeWork
154 sg:pub.10.1007/s10853-018-2899-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1106984316
155 https://doi.org/10.1007/s10853-018-2899-7
156 rdf:type schema:CreativeWork
157 sg:pub.10.1007/s10971-016-4095-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1032743230
158 https://doi.org/10.1007/s10971-016-4095-z
159 rdf:type schema:CreativeWork
160 sg:pub.10.1007/s11051-011-0715-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018504952
161 https://doi.org/10.1007/s11051-011-0715-2
162 rdf:type schema:CreativeWork
163 sg:pub.10.1038/srep20897 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021571155
164 https://doi.org/10.1038/srep20897
165 rdf:type schema:CreativeWork
166 https://app.dimensions.ai/details/publication/pub.1024339857 schema:CreativeWork
167 https://doi.org/10.1002/macp.201200494 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004900275
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1016/0012-821x(79)90168-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044015899
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1016/0304-8853(83)90698-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035886310
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1016/0378-4363(77)90759-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021838589
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1016/j.cplett.2004.04.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031489988
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1016/j.eurpolymj.2017.07.022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090741766
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1016/j.jallcom.2009.11.119 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004649239
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1016/j.jmmm.2012.04.049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047517263
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1016/j.matchar.2014.12.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042078475
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1016/j.matchemphys.2014.07.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004886528
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1016/j.matchemphys.2017.12.089 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100108903
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1016/j.msec.2017.04.066 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084924837
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1016/j.partic.2016.06.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043261891
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1016/j.polymer.2014.12.047 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033291389
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1016/j.snb.2013.07.091 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024635395
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1016/s0032-5910(03)00048-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033916773
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1016/s0304-8853(97)00180-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045946334
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1021/acs.jpclett.6b00644 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055114366
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1021/acs.nanolett.5b00331 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055120589
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1021/cm050060+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1055411293
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1021/ja0380852 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038558732
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1021/jp501652e schema:sameAs https://app.dimensions.ai/details/publication/pub.1056100010
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1029/gl011i003p00185 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026898978
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1046/j.1365-246x.2000.00081.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1041676207
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1063/1.1599959 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057724483
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1063/1.1853931 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057828254
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1063/1.2172891 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057842594
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1063/1.4797628 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058072955
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1088/0022-3727/36/13/202 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049456758
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1088/0022-3727/40/19/001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042131266
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1088/0953-8984/14/12/203 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039498413
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1088/0953-8984/16/7/r01 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005548196
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1103/physrevb.40.9090 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060552724
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1103/physrevb.43.8461 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060558164
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1103/physrevb.74.064425 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060618429
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1103/physrevb.98.134423 schema:sameAs https://app.dimensions.ai/details/publication/pub.1107639104
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1109/tmag.1979.1060319 schema:sameAs https://app.dimensions.ai/details/publication/pub.1061669466
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1143/jpsj.41.1894 schema:sameAs https://app.dimensions.ai/details/publication/pub.1063102461
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1155/2016/7840161 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043052062
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1166/jnn.2008.15348 schema:sameAs https://app.dimensions.ai/details/publication/pub.1077684958
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1557/proc-746-q4.1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067955157
248 rdf:type schema:CreativeWork
249 https://doi.org/10.3390/gels1010024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002423118
250 rdf:type schema:CreativeWork
251 https://doi.org/10.3390/s8095775 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052207153
252 rdf:type schema:CreativeWork
253 https://www.grid.ac/institutes/grid.182470.8 schema:alternateName National Interuniversity Consortium of Materials Science and Technology
254 schema:name National Interuniversity Consortium of Materials Science and Technology, INSTM, Via Giusti 9, 50121, Florence, Italy
255 rdf:type schema:Organization
256 https://www.grid.ac/institutes/grid.425358.d schema:alternateName Istituto Nazionale di Ricerca Metrologica
257 schema:name Advanced Materials for Metrology and Life Sciences, INRiM, Strada delle Cacce 91, 10135, Turin, Italy
258 rdf:type schema:Organization
259 https://www.grid.ac/institutes/grid.4800.c schema:alternateName Polytechnic University of Turin
260 schema:name DISAT, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129, Turin, Italy
261 National Interuniversity Consortium of Materials Science and Technology, INSTM, Via Giusti 9, 50121, Florence, Italy
262 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...