Mechanochemical synthesis of methylammonium lead iodide perovskite View Full Text


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Article Info

DATE

2016-07-01

AUTHORS

K. V. Manukyan, A. V. Yeghishyan, D. O. Moskovskikh, J. Kapaldo, A. Mintairov, A. S. Mukasyan

ABSTRACT

A mechanically induced solid-state reaction method for the synthesis of organic–inorganic hybrid perovskites, such as methylammonium lead iodide (CH3NH3PbI3) is reported. The perovskites were synthesized both in bulk and Al2O3-supported forms. The phase- and structural-formation mechanisms of such perovskites are also investigated. The experiments suggest that diffusion of PbI2 into CH3NH3I crystals is a rate-limiting step of the reaction process. It is also shown that water (humidity) significantly influences the reaction kinetics. UV–Vis–NIR absorption and photoluminescence spectroscopies indicate that the band edge and emission characteristics of the as-fabricated materials strongly depend on their particle size. More... »

PAGES

9123-9130

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10853-016-0165-4

DOI

http://dx.doi.org/10.1007/s10853-016-0165-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005661599


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