Ontology type: schema:ScholarlyArticle
2016-07-01
AUTHORSK. V. Manukyan, A. V. Yeghishyan, D. O. Moskovskikh, J. Kapaldo, A. Mintairov, A. S. Mukasyan
ABSTRACTA mechanically induced solid-state reaction method for the synthesis of organic–inorganic hybrid perovskites, such as methylammonium lead iodide (CH3NH3PbI3) is reported. The perovskites were synthesized both in bulk and Al2O3-supported forms. The phase- and structural-formation mechanisms of such perovskites are also investigated. The experiments suggest that diffusion of PbI2 into CH3NH3I crystals is a rate-limiting step of the reaction process. It is also shown that water (humidity) significantly influences the reaction kinetics. UV–Vis–NIR absorption and photoluminescence spectroscopies indicate that the band edge and emission characteristics of the as-fabricated materials strongly depend on their particle size. More... »
PAGES9123-9130
http://scigraph.springernature.com/pub.10.1007/s10853-016-0165-4
DOIhttp://dx.doi.org/10.1007/s10853-016-0165-4
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