Roles of alloying additions on local structure and glass-forming ability of Cu–Zr metallic glasses View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-09-17

AUTHORS

B. F. Lu, L. T. Kong, Z. Jiang, Y. Y. Huang, J. F. Li, Y. H. Zhou

ABSTRACT

To identify the structural role of alloying element M (M = Ti, Ga, Co, Fe) on the glass-forming ability (GFA) of Cu50Zr50 base alloy, the atomic structures of the binary and ternary metallic glasses were examined by extended X-ray absorption fine structure (EXAFS) spectroscopy. The EXAFS curve-fitting analysis indicates that the main structural difference among the metallic glasses is in the atomic packing density of Cu-centered clusters. The relative shortening of the Cu–M distance is closely related to the heat of mixing between Cu and M: the more negative the heat of mixing, the larger is the shortening of the Cu–M distance. Based on a systematic analysis of the component properties and GFA data for Cu–Zr based alloys, it is suggested that alloying elements that bring a more uniform distribution of atomic size and possess strong chemical interactions with the main components should be selected in developing large-size bulk metallic glasses. More... »

PAGES

496-503

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10853-013-7725-7

DOI

http://dx.doi.org/10.1007/s10853-013-7725-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047775955


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