Effects of sintering aids on the densification of Mo–Si–B alloys View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-12

AUTHORS

Jae-Il Jung, Naixie Zhou, Jian Luo

ABSTRACT

The effects of seven sintering aids (0.5 at.% Ni, Co, Fe, Cr, Zr, Nb, and Pd) on the densification of Mo–Si–B alloys of six different compositions (Mo, Mo–0.2Si, Mo–0.2Si–0.02B, Mo–2.5Si–2.5B, Mo–7Si–5B, and Mo–8.9Si–7.7B at.%) are systematically investigated. It was found that Ni, Co, and Fe are effective in enhancing densification of Mo–Si–B alloys, and Ni is the most effective sintering aid. This study supports a previously proposed hypothesis that activated sintering results from enhanced mass transport in the sintering-aid-induced quasi-liquid intergranular films (a type of grain boundary complexion). The relative effectiveness of these sintering aids can be rationalized by analyzing several key thermodynamic parameters that control the stability of premelting-like grain boundary complexions. Future studies are needed to develop interfacial thermodynamic models and methods for computing “grain boundary complexion (phase) diagrams” for multicomponent systems, which can be a useful component for the “Materials Genome” project that will enable better predictions of the activated sintering and other materials phenomena. More... »

PAGES

8308-8319

Journal

TITLE

Journal of Materials Science

ISSUE

24

VOLUME

47

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10853-012-6815-2

DOI

http://dx.doi.org/10.1007/s10853-012-6815-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049735362


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