Electrochemical and morphological studies of an electroactive material derived from 3-hydroxyphenylacetic acid: a new matrix for oligonucleotide hybridization View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-01

AUTHORS

Ronalt M. L. Oliveira, Sabrina N. Vieira, Heden C. Alves, Erick G. França, Diego L. Franco, Lucas F. Ferreira, Ana G. Brito-Madurro, João M. Madurro

ABSTRACT

This paper describes the formation of polymeric films derived from 3-hydroxyphenylacetic acid electropolymerized onto graphite electrodes through cyclic voltammetry. We observed the formation of an electroactive material over the electrode surface. The modified electrode showed significant blocking behavior to electron transfer reaction of the pair redox ferricyanide/ferrocyanide, indicating repulsion electrostatic with the negatively charged carboxylate groups of the polymer. The quasi-reversible behavior to Ru(NH3)6Cl2 suggests electrostatic attraction, facilitating the charge transfer. The modified electrode was studied through electrochemical quartz crystal microbalance, electrochemical impedance spectroscopy, and atomic force microscopy. These analyses indicate modification of the graphite electrode. Surface analysis by AFM showed that the morphology of the modified electrode surface presents globular form, randomly distributed, and formed by lower globules with diameter near 100 nm. Immobilization and hybridization of oligonucleotide onto the modified electrode were successfully carried out by using both direct electrochemical oxidation of nitrogenated bases and the redox electroactive indicator methylene blue. More... »

PAGES

475-482

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10853-009-3964-z

DOI

http://dx.doi.org/10.1007/s10853-009-3964-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013424058


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Oliveira", 
        "givenName": "Ronalt M. L.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vieira", 
        "givenName": "Sabrina N.", 
        "id": "sg:person.010055311614.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010055311614.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Alves", 
        "givenName": "Heden C.", 
        "id": "sg:person.013025611515.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013025611515.84"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fran\u00e7a", 
        "givenName": "Erick G.", 
        "id": "sg:person.015525244461.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015525244461.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Franco", 
        "givenName": "Diego L.", 
        "id": "sg:person.016207276605.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016207276605.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ferreira", 
        "givenName": "Lucas F.", 
        "id": "sg:person.0646114447.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0646114447.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Genetics and Biochemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brito-Madurro", 
        "givenName": "Ana G.", 
        "id": "sg:person.07516431747.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07516431747.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Federal University of Uberl\u00e2ndia", 
          "id": "https://www.grid.ac/institutes/grid.411284.a", 
          "name": [
            "Institute of Chemistry, Federal University of Uberl\u00e2ndia, 38400-902, Uberl\u00e2ndia, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Madurro", 
        "givenName": "Jo\u00e3o M.", 
        "id": "sg:person.011111372747.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011111372747.42"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s1388-2481(02)00428-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003904882"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1388-2481(02)00428-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003904882"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2008.08.015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004127186"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1381-1169(99)00354-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004314891"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0003-2670(00)01058-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004511441"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja037723d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004613979"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja037723d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004613979"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0379-6779(99)00170-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005875055"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/masy.200651333", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005953976"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molcata.2004.04.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006717735"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pen.21026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006921664"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pen.21044", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007348180"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/elan.200403001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009425763"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0956-5663(03)00121-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010776374"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0956-5663(03)00121-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010776374"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ab.2004.06.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011404800"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matchemphys.2007.08.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013818035"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.msec.2008.09.048", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016554046"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01337937", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018027660", 
          "https://doi.org/10.1007/bf01337937"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2008.10.029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022179305"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.elecom.2008.03.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024578448"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.biomaterials.2006.09.046", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025122248"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.talanta.2008.07.024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028232444"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ab.2008.10.043", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033821755"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-007-1880-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034260201", 
          "https://doi.org/10.1007/s10853-007-1880-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3390/ijms9071173", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034491182"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/elan.200804238", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039540694"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-006-0235-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043291295", 
          "https://doi.org/10.1007/s10853-006-0235-0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-006-0235-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043291295", 
          "https://doi.org/10.1007/s10853-006-0235-0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-4109(200103)13:3<219::aid-elan219>3.0.co;2-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045289304"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-4109(200103)13:3<219::aid-elan219>3.0.co;2-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045289304"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0956-5663(01)00312-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047001085"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2008.03.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048364674"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.elecom.2008.03.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048995953"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.snb.2008.09.007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050681350"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/elan.200603855", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052884990"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac0123936", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054992943"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac0123936", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054992943"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac070403i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054999317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac070403i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054999317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.94.036106", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060829756"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.94.036106", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060829756"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-01", 
    "datePublishedReg": "2010-01-01", 
    "description": "This paper describes the formation of polymeric films derived from 3-hydroxyphenylacetic acid electropolymerized onto graphite electrodes through cyclic voltammetry. We observed the formation of an electroactive material over the electrode surface. The modified electrode showed significant blocking behavior to electron transfer reaction of the pair redox ferricyanide/ferrocyanide, indicating repulsion electrostatic with the negatively charged carboxylate groups of the polymer. The quasi-reversible behavior to Ru(NH3)6Cl2 suggests electrostatic attraction, facilitating the charge transfer. The modified electrode was studied through electrochemical quartz crystal microbalance, electrochemical impedance spectroscopy, and atomic force microscopy. These analyses indicate modification of the graphite electrode. Surface analysis by AFM showed that the morphology of the modified electrode surface presents globular form, randomly distributed, and formed by lower globules with diameter near 100 nm. Immobilization and hybridization of oligonucleotide onto the modified electrode were successfully carried out by using both direct electrochemical oxidation of nitrogenated bases and the redox electroactive indicator methylene blue.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10853-009-3964-z", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312116", 
        "issn": [
          "0022-2461", 
          "1573-4811"
        ], 
        "name": "Journal of Materials Science", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "45"
      }
    ], 
    "name": "Electrochemical and morphological studies of an electroactive material derived from 3-hydroxyphenylacetic acid: a new matrix for oligonucleotide hybridization", 
    "pagination": "475-482", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10853-009-3964-z"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3ff305d539721a952cd3dac4e078d7e10cd6830fd7b219e1cd28d1b8ec8f98f6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1013424058"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10853-009-3964-z", 
      "https://app.dimensions.ai/details/publication/pub.1013424058"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T09:26", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000376_0000000376/records_56193_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs10853-009-3964-z"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10853-009-3964-z'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10853-009-3964-z'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10853-009-3964-z'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10853-009-3964-z'


 

This table displays all metadata directly associated to this object as RDF triples.

215 TRIPLES      21 PREDICATES      61 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10853-009-3964-z schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N58d804e712494032b6475172b78b0716
4 schema:citation sg:pub.10.1007/bf01337937
5 sg:pub.10.1007/s10853-006-0235-0
6 sg:pub.10.1007/s10853-007-1880-7
7 https://doi.org/10.1002/1521-4109(200103)13:3<219::aid-elan219>3.0.co;2-7
8 https://doi.org/10.1002/elan.200403001
9 https://doi.org/10.1002/elan.200603855
10 https://doi.org/10.1002/elan.200804238
11 https://doi.org/10.1002/masy.200651333
12 https://doi.org/10.1002/pen.21026
13 https://doi.org/10.1002/pen.21044
14 https://doi.org/10.1016/j.ab.2004.06.021
15 https://doi.org/10.1016/j.ab.2008.10.043
16 https://doi.org/10.1016/j.biomaterials.2006.09.046
17 https://doi.org/10.1016/j.elecom.2008.03.006
18 https://doi.org/10.1016/j.elecom.2008.03.010
19 https://doi.org/10.1016/j.electacta.2008.03.005
20 https://doi.org/10.1016/j.electacta.2008.08.015
21 https://doi.org/10.1016/j.eurpolymj.2008.10.029
22 https://doi.org/10.1016/j.matchemphys.2007.08.006
23 https://doi.org/10.1016/j.molcata.2004.04.001
24 https://doi.org/10.1016/j.msec.2008.09.048
25 https://doi.org/10.1016/j.snb.2008.09.007
26 https://doi.org/10.1016/j.talanta.2008.07.024
27 https://doi.org/10.1016/s0003-2670(00)01058-8
28 https://doi.org/10.1016/s0379-6779(99)00170-8
29 https://doi.org/10.1016/s0956-5663(01)00312-8
30 https://doi.org/10.1016/s0956-5663(03)00121-0
31 https://doi.org/10.1016/s1381-1169(99)00354-4
32 https://doi.org/10.1016/s1388-2481(02)00428-9
33 https://doi.org/10.1021/ac0123936
34 https://doi.org/10.1021/ac070403i
35 https://doi.org/10.1021/ja037723d
36 https://doi.org/10.1103/physrevlett.94.036106
37 https://doi.org/10.3390/ijms9071173
38 schema:datePublished 2010-01
39 schema:datePublishedReg 2010-01-01
40 schema:description This paper describes the formation of polymeric films derived from 3-hydroxyphenylacetic acid electropolymerized onto graphite electrodes through cyclic voltammetry. We observed the formation of an electroactive material over the electrode surface. The modified electrode showed significant blocking behavior to electron transfer reaction of the pair redox ferricyanide/ferrocyanide, indicating repulsion electrostatic with the negatively charged carboxylate groups of the polymer. The quasi-reversible behavior to Ru(NH3)6Cl2 suggests electrostatic attraction, facilitating the charge transfer. The modified electrode was studied through electrochemical quartz crystal microbalance, electrochemical impedance spectroscopy, and atomic force microscopy. These analyses indicate modification of the graphite electrode. Surface analysis by AFM showed that the morphology of the modified electrode surface presents globular form, randomly distributed, and formed by lower globules with diameter near 100 nm. Immobilization and hybridization of oligonucleotide onto the modified electrode were successfully carried out by using both direct electrochemical oxidation of nitrogenated bases and the redox electroactive indicator methylene blue.
41 schema:genre research_article
42 schema:inLanguage en
43 schema:isAccessibleForFree false
44 schema:isPartOf N69aab5527c1a48daadac64a36f162129
45 Na56f4999c4f74f30913f32ce4b406d75
46 sg:journal.1312116
47 schema:name Electrochemical and morphological studies of an electroactive material derived from 3-hydroxyphenylacetic acid: a new matrix for oligonucleotide hybridization
48 schema:pagination 475-482
49 schema:productId N083beb8697bf4537870122ebec63c3a0
50 N0f5ef31ff5be49f28c1f26fe372c8d77
51 Na01273bc7baf4c0c800460a17381167a
52 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013424058
53 https://doi.org/10.1007/s10853-009-3964-z
54 schema:sdDatePublished 2019-04-15T09:26
55 schema:sdLicense https://scigraph.springernature.com/explorer/license/
56 schema:sdPublisher Nd50c102af1fb4e63871f2cedac0be102
57 schema:url https://link.springer.com/10.1007%2Fs10853-009-3964-z
58 sgo:license sg:explorer/license/
59 sgo:sdDataset articles
60 rdf:type schema:ScholarlyArticle
61 N078a3faaba7c43eebacfd9e68bdcfc0d rdf:first sg:person.0646114447.02
62 rdf:rest N7e5c50b65fa744f7b7a9b4fc5bed7553
63 N083beb8697bf4537870122ebec63c3a0 schema:name readcube_id
64 schema:value 3ff305d539721a952cd3dac4e078d7e10cd6830fd7b219e1cd28d1b8ec8f98f6
65 rdf:type schema:PropertyValue
66 N0f5ef31ff5be49f28c1f26fe372c8d77 schema:name dimensions_id
67 schema:value pub.1013424058
68 rdf:type schema:PropertyValue
69 N3baf36135061446f8ae314954a6b52d0 rdf:first sg:person.013025611515.84
70 rdf:rest N70ac4c7fb27d49e0b892fa3155a2b0e3
71 N58d804e712494032b6475172b78b0716 rdf:first Ne7303a7f54354f6bb4abc291602d20b5
72 rdf:rest N8ef6c7f97a2245ddaf0651f312d95896
73 N61f99853f9cb4f1e98b78600c9849f59 rdf:first sg:person.011111372747.42
74 rdf:rest rdf:nil
75 N69aab5527c1a48daadac64a36f162129 schema:volumeNumber 45
76 rdf:type schema:PublicationVolume
77 N70ac4c7fb27d49e0b892fa3155a2b0e3 rdf:first sg:person.015525244461.11
78 rdf:rest Ne3872c356f564e1fa4a518f26ad4cc75
79 N7e5c50b65fa744f7b7a9b4fc5bed7553 rdf:first sg:person.07516431747.46
80 rdf:rest N61f99853f9cb4f1e98b78600c9849f59
81 N8ef6c7f97a2245ddaf0651f312d95896 rdf:first sg:person.010055311614.02
82 rdf:rest N3baf36135061446f8ae314954a6b52d0
83 Na01273bc7baf4c0c800460a17381167a schema:name doi
84 schema:value 10.1007/s10853-009-3964-z
85 rdf:type schema:PropertyValue
86 Na56f4999c4f74f30913f32ce4b406d75 schema:issueNumber 2
87 rdf:type schema:PublicationIssue
88 Nd50c102af1fb4e63871f2cedac0be102 schema:name Springer Nature - SN SciGraph project
89 rdf:type schema:Organization
90 Ne3872c356f564e1fa4a518f26ad4cc75 rdf:first sg:person.016207276605.48
91 rdf:rest N078a3faaba7c43eebacfd9e68bdcfc0d
92 Ne7303a7f54354f6bb4abc291602d20b5 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
93 schema:familyName Oliveira
94 schema:givenName Ronalt M. L.
95 rdf:type schema:Person
96 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
97 schema:name Chemical Sciences
98 rdf:type schema:DefinedTerm
99 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
100 schema:name Physical Chemistry (incl. Structural)
101 rdf:type schema:DefinedTerm
102 sg:journal.1312116 schema:issn 0022-2461
103 1573-4811
104 schema:name Journal of Materials Science
105 rdf:type schema:Periodical
106 sg:person.010055311614.02 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
107 schema:familyName Vieira
108 schema:givenName Sabrina N.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010055311614.02
110 rdf:type schema:Person
111 sg:person.011111372747.42 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
112 schema:familyName Madurro
113 schema:givenName João M.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011111372747.42
115 rdf:type schema:Person
116 sg:person.013025611515.84 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
117 schema:familyName Alves
118 schema:givenName Heden C.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013025611515.84
120 rdf:type schema:Person
121 sg:person.015525244461.11 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
122 schema:familyName França
123 schema:givenName Erick G.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015525244461.11
125 rdf:type schema:Person
126 sg:person.016207276605.48 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
127 schema:familyName Franco
128 schema:givenName Diego L.
129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016207276605.48
130 rdf:type schema:Person
131 sg:person.0646114447.02 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
132 schema:familyName Ferreira
133 schema:givenName Lucas F.
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0646114447.02
135 rdf:type schema:Person
136 sg:person.07516431747.46 schema:affiliation https://www.grid.ac/institutes/grid.411284.a
137 schema:familyName Brito-Madurro
138 schema:givenName Ana G.
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07516431747.46
140 rdf:type schema:Person
141 sg:pub.10.1007/bf01337937 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018027660
142 https://doi.org/10.1007/bf01337937
143 rdf:type schema:CreativeWork
144 sg:pub.10.1007/s10853-006-0235-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043291295
145 https://doi.org/10.1007/s10853-006-0235-0
146 rdf:type schema:CreativeWork
147 sg:pub.10.1007/s10853-007-1880-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034260201
148 https://doi.org/10.1007/s10853-007-1880-7
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1002/1521-4109(200103)13:3<219::aid-elan219>3.0.co;2-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045289304
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1002/elan.200403001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009425763
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1002/elan.200603855 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052884990
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1002/elan.200804238 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039540694
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1002/masy.200651333 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005953976
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1002/pen.21026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006921664
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1002/pen.21044 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007348180
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1016/j.ab.2004.06.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011404800
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1016/j.ab.2008.10.043 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033821755
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1016/j.biomaterials.2006.09.046 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025122248
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1016/j.elecom.2008.03.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048995953
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1016/j.elecom.2008.03.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024578448
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1016/j.electacta.2008.03.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048364674
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1016/j.electacta.2008.08.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004127186
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1016/j.eurpolymj.2008.10.029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022179305
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1016/j.matchemphys.2007.08.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013818035
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1016/j.molcata.2004.04.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006717735
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1016/j.msec.2008.09.048 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016554046
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1016/j.snb.2008.09.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050681350
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1016/j.talanta.2008.07.024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028232444
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1016/s0003-2670(00)01058-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004511441
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1016/s0379-6779(99)00170-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005875055
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1016/s0956-5663(01)00312-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047001085
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1016/s0956-5663(03)00121-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010776374
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1016/s1381-1169(99)00354-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004314891
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1016/s1388-2481(02)00428-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003904882
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1021/ac0123936 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054992943
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1021/ac070403i schema:sameAs https://app.dimensions.ai/details/publication/pub.1054999317
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1021/ja037723d schema:sameAs https://app.dimensions.ai/details/publication/pub.1004613979
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1103/physrevlett.94.036106 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060829756
209 rdf:type schema:CreativeWork
210 https://doi.org/10.3390/ijms9071173 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034491182
211 rdf:type schema:CreativeWork
212 https://www.grid.ac/institutes/grid.411284.a schema:alternateName Federal University of Uberlândia
213 schema:name Institute of Chemistry, Federal University of Uberlândia, 38400-902, Uberlândia, Brazil
214 Institute of Genetics and Biochemistry, Federal University of Uberlândia, 38400-902, Uberlândia, Brazil
215 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...