Preparation and properties of biodegradable poly(lactic acid)/poly(butylene adipate-co-terephthalate) blend with glycidyl methacrylate as reactive processing agent View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-11-10

AUTHORS

Naiwen Zhang, Qinfeng Wang, Jie Ren, Liang Wang

ABSTRACT

Poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) were melt-blended in the presence of glycidyl methacrylate (GMA) by twin-screw extrusion. The physical properties, phase morphology, thermal properties, and melt rheological behavior of the blends were investigated by tensile tests, Charpy impact tests, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and advanced rheology expended system (ARES). With 2 or 5 wt% GMA, the tensile toughness of the PLA/PBAT blend was greatly increased without severe loss in tensile strength. The impact strength of the blend was also significantly improved at 1 wt% of GMA addition but ultimately trended to be saturated with increasing GMA. SEM micrographs revealed that better miscibility and more shear yielding mechanism were involved in the toughening of the blend. DSC results indicated that the blend is still a two-phase system in the presence of reaction agent and the addition of GMA was found to enhance the interfacial adhesion between PLA and PBAT. Rheological results revealed that the addition of T-GMA increased the storage moduli (G′), loss moduli (G′′) and complex viscosity of the blends at nearly all frequencies. The decreased shear-thinning tendency of the blends in the presence of T-GMA also implied improved melt stability during processing. More... »

PAGES

250-256

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10853-008-3049-4

DOI

http://dx.doi.org/10.1007/s10853-008-3049-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013749126


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.24516.34", 
          "name": [
            "Institute of Nano- and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
            "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Naiwen", 
        "id": "sg:person.012171701345.32", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012171701345.32"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.24516.34", 
          "name": [
            "Institute of Nano- and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
            "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Qinfeng", 
        "id": "sg:person.014362222745.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014362222745.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.24516.34", 
          "name": [
            "Institute of Nano- and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
            "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ren", 
        "givenName": "Jie", 
        "id": "sg:person.012310247642.89", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012310247642.89"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.24516.34", 
          "name": [
            "Institute of Nano- and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China", 
            "Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Liang", 
        "id": "sg:person.012240014545.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012240014545.39"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf01352202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028057432", 
          "https://doi.org/10.1007/bf01352202"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01184979", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048300176", 
          "https://doi.org/10.1007/bf01184979"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00550456", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039200738", 
          "https://doi.org/10.1007/bf00550456"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00376274", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044655804", 
          "https://doi.org/10.1007/bf00376274"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/b:jooe.0000010051.46648.0e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013249078", 
          "https://doi.org/10.1023/b:jooe.0000010051.46648.0e"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00551799", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007680532", 
          "https://doi.org/10.1007/bf00551799"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-11-10", 
    "datePublishedReg": "2008-11-10", 
    "description": "Poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) were melt-blended in the presence of glycidyl methacrylate (GMA) by twin-screw extrusion. The physical properties, phase morphology, thermal properties, and melt rheological behavior of the blends were investigated by tensile tests, Charpy impact tests, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and advanced rheology expended system (ARES). With 2 or 5 wt% GMA, the tensile toughness of the PLA/PBAT blend was greatly increased without severe loss in tensile strength. The impact strength of the blend was also significantly improved at 1 wt% of GMA addition but ultimately trended to be saturated with increasing GMA. SEM micrographs revealed that better miscibility and more shear yielding mechanism were involved in the toughening of the blend. DSC results indicated that the blend is still a two-phase system in the presence of reaction agent and the addition of GMA was found to enhance the interfacial adhesion between PLA and PBAT. Rheological results revealed that the addition of T-GMA increased the storage moduli (G\u2032), loss moduli (G\u2032\u2032) and complex viscosity of the blends at nearly all frequencies. The decreased shear-thinning tendency of the blends in the presence of T-GMA also implied improved melt stability during processing.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10853-008-3049-4", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1312116", 
        "issn": [
          "0022-2461", 
          "1573-4803"
        ], 
        "name": "Journal of Materials Science", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "44"
      }
    ], 
    "keywords": [
      "reactive processing agents", 
      "PLA/PBAT blends", 
      "Charpy impact test", 
      "shear-thinning tendency", 
      "twin-screw extrusion", 
      "shear yielding mechanism", 
      "glycidyl methacrylate", 
      "differential scanning calorimetry", 
      "melt rheological behavior", 
      "addition of GMA", 
      "interfacial adhesion", 
      "tensile tests", 
      "impact strength", 
      "impact tests", 
      "tensile toughness", 
      "tensile strength", 
      "yielding mechanism", 
      "PBAT blends", 
      "storage modulus", 
      "phase morphology", 
      "advanced rheology", 
      "loss modulus", 
      "thermal properties", 
      "complex viscosity", 
      "rheological behavior", 
      "two-phase system", 
      "SEM micrographs", 
      "rheological results", 
      "GMA addition", 
      "good miscibility", 
      "blends", 
      "reaction agent", 
      "modulus", 
      "melt stability", 
      "electron microscopy", 
      "DSC results", 
      "physical properties", 
      "scanning calorimetry", 
      "strength", 
      "properties", 
      "toughness", 
      "toughening", 
      "processing agent", 
      "PBAT", 
      "rheology", 
      "methacrylate", 
      "viscosity", 
      "extrusion", 
      "PLA", 
      "miscibility", 
      "micrographs", 
      "system", 
      "melt", 
      "stability", 
      "test", 
      "microscopy", 
      "morphology", 
      "adhesion", 
      "calorimetry", 
      "processing", 
      "addition", 
      "results", 
      "behavior", 
      "frequency", 
      "preparation", 
      "presence", 
      "loss", 
      "mechanism", 
      "severe loss", 
      "tendency", 
      "agents"
    ], 
    "name": "Preparation and properties of biodegradable poly(lactic acid)/poly(butylene adipate-co-terephthalate) blend with glycidyl methacrylate as reactive processing agent", 
    "pagination": "250-256", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1013749126"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10853-008-3049-4"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10853-008-3049-4", 
      "https://app.dimensions.ai/details/publication/pub.1013749126"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-09-02T15:52", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_461.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10853-008-3049-4"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10853-008-3049-4'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10853-008-3049-4'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10853-008-3049-4'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10853-008-3049-4'


 

This table displays all metadata directly associated to this object as RDF triples.

174 TRIPLES      21 PREDICATES      101 URIs      87 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10853-008-3049-4 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N7644e48a8b8841aaa19622ff5439004c
4 schema:citation sg:pub.10.1007/bf00376274
5 sg:pub.10.1007/bf00550456
6 sg:pub.10.1007/bf00551799
7 sg:pub.10.1007/bf01184979
8 sg:pub.10.1007/bf01352202
9 sg:pub.10.1023/b:jooe.0000010051.46648.0e
10 schema:datePublished 2008-11-10
11 schema:datePublishedReg 2008-11-10
12 schema:description Poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) were melt-blended in the presence of glycidyl methacrylate (GMA) by twin-screw extrusion. The physical properties, phase morphology, thermal properties, and melt rheological behavior of the blends were investigated by tensile tests, Charpy impact tests, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and advanced rheology expended system (ARES). With 2 or 5 wt% GMA, the tensile toughness of the PLA/PBAT blend was greatly increased without severe loss in tensile strength. The impact strength of the blend was also significantly improved at 1 wt% of GMA addition but ultimately trended to be saturated with increasing GMA. SEM micrographs revealed that better miscibility and more shear yielding mechanism were involved in the toughening of the blend. DSC results indicated that the blend is still a two-phase system in the presence of reaction agent and the addition of GMA was found to enhance the interfacial adhesion between PLA and PBAT. Rheological results revealed that the addition of T-GMA increased the storage moduli (G′), loss moduli (G′′) and complex viscosity of the blends at nearly all frequencies. The decreased shear-thinning tendency of the blends in the presence of T-GMA also implied improved melt stability during processing.
13 schema:genre article
14 schema:isAccessibleForFree false
15 schema:isPartOf N875b133fc3e142d6ba587604c8dbbc45
16 Nc1b5d08d9501436c9b516150a729e1b0
17 sg:journal.1312116
18 schema:keywords Charpy impact test
19 DSC results
20 GMA addition
21 PBAT
22 PBAT blends
23 PLA
24 PLA/PBAT blends
25 SEM micrographs
26 addition
27 addition of GMA
28 adhesion
29 advanced rheology
30 agents
31 behavior
32 blends
33 calorimetry
34 complex viscosity
35 differential scanning calorimetry
36 electron microscopy
37 extrusion
38 frequency
39 glycidyl methacrylate
40 good miscibility
41 impact strength
42 impact tests
43 interfacial adhesion
44 loss
45 loss modulus
46 mechanism
47 melt
48 melt rheological behavior
49 melt stability
50 methacrylate
51 micrographs
52 microscopy
53 miscibility
54 modulus
55 morphology
56 phase morphology
57 physical properties
58 preparation
59 presence
60 processing
61 processing agent
62 properties
63 reaction agent
64 reactive processing agents
65 results
66 rheological behavior
67 rheological results
68 rheology
69 scanning calorimetry
70 severe loss
71 shear yielding mechanism
72 shear-thinning tendency
73 stability
74 storage modulus
75 strength
76 system
77 tendency
78 tensile strength
79 tensile tests
80 tensile toughness
81 test
82 thermal properties
83 toughening
84 toughness
85 twin-screw extrusion
86 two-phase system
87 viscosity
88 yielding mechanism
89 schema:name Preparation and properties of biodegradable poly(lactic acid)/poly(butylene adipate-co-terephthalate) blend with glycidyl methacrylate as reactive processing agent
90 schema:pagination 250-256
91 schema:productId N2bcf959d649b4d719473e417d394d8de
92 Nb13035752e694493ba8146dc7b44ec42
93 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013749126
94 https://doi.org/10.1007/s10853-008-3049-4
95 schema:sdDatePublished 2022-09-02T15:52
96 schema:sdLicense https://scigraph.springernature.com/explorer/license/
97 schema:sdPublisher Nb397a84161af4b178154c384861a30c6
98 schema:url https://doi.org/10.1007/s10853-008-3049-4
99 sgo:license sg:explorer/license/
100 sgo:sdDataset articles
101 rdf:type schema:ScholarlyArticle
102 N2bcf959d649b4d719473e417d394d8de schema:name dimensions_id
103 schema:value pub.1013749126
104 rdf:type schema:PropertyValue
105 N64782fb50bb34b3eacc4ad088bf67869 rdf:first sg:person.014362222745.86
106 rdf:rest N8acdcb4806084a53967adc4d5924f4df
107 N7644e48a8b8841aaa19622ff5439004c rdf:first sg:person.012171701345.32
108 rdf:rest N64782fb50bb34b3eacc4ad088bf67869
109 N875b133fc3e142d6ba587604c8dbbc45 schema:issueNumber 1
110 rdf:type schema:PublicationIssue
111 N8acdcb4806084a53967adc4d5924f4df rdf:first sg:person.012310247642.89
112 rdf:rest N941dabe9615c4af3adb04f3468cd5f83
113 N941dabe9615c4af3adb04f3468cd5f83 rdf:first sg:person.012240014545.39
114 rdf:rest rdf:nil
115 Nb13035752e694493ba8146dc7b44ec42 schema:name doi
116 schema:value 10.1007/s10853-008-3049-4
117 rdf:type schema:PropertyValue
118 Nb397a84161af4b178154c384861a30c6 schema:name Springer Nature - SN SciGraph project
119 rdf:type schema:Organization
120 Nc1b5d08d9501436c9b516150a729e1b0 schema:volumeNumber 44
121 rdf:type schema:PublicationVolume
122 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
123 schema:name Engineering
124 rdf:type schema:DefinedTerm
125 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
126 schema:name Materials Engineering
127 rdf:type schema:DefinedTerm
128 sg:journal.1312116 schema:issn 0022-2461
129 1573-4803
130 schema:name Journal of Materials Science
131 schema:publisher Springer Nature
132 rdf:type schema:Periodical
133 sg:person.012171701345.32 schema:affiliation grid-institutes:grid.24516.34
134 schema:familyName Zhang
135 schema:givenName Naiwen
136 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012171701345.32
137 rdf:type schema:Person
138 sg:person.012240014545.39 schema:affiliation grid-institutes:grid.24516.34
139 schema:familyName Wang
140 schema:givenName Liang
141 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012240014545.39
142 rdf:type schema:Person
143 sg:person.012310247642.89 schema:affiliation grid-institutes:grid.24516.34
144 schema:familyName Ren
145 schema:givenName Jie
146 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012310247642.89
147 rdf:type schema:Person
148 sg:person.014362222745.86 schema:affiliation grid-institutes:grid.24516.34
149 schema:familyName Wang
150 schema:givenName Qinfeng
151 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014362222745.86
152 rdf:type schema:Person
153 sg:pub.10.1007/bf00376274 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044655804
154 https://doi.org/10.1007/bf00376274
155 rdf:type schema:CreativeWork
156 sg:pub.10.1007/bf00550456 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039200738
157 https://doi.org/10.1007/bf00550456
158 rdf:type schema:CreativeWork
159 sg:pub.10.1007/bf00551799 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007680532
160 https://doi.org/10.1007/bf00551799
161 rdf:type schema:CreativeWork
162 sg:pub.10.1007/bf01184979 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048300176
163 https://doi.org/10.1007/bf01184979
164 rdf:type schema:CreativeWork
165 sg:pub.10.1007/bf01352202 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028057432
166 https://doi.org/10.1007/bf01352202
167 rdf:type schema:CreativeWork
168 sg:pub.10.1023/b:jooe.0000010051.46648.0e schema:sameAs https://app.dimensions.ai/details/publication/pub.1013249078
169 https://doi.org/10.1023/b:jooe.0000010051.46648.0e
170 rdf:type schema:CreativeWork
171 grid-institutes:grid.24516.34 schema:alternateName Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People’s Republic of China
172 schema:name Institute of Nano- and Bio-Polymeric Materials, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People’s Republic of China
173 Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, School of Material Science and Engineering, Tongji University, 200092, Shanghai, People’s Republic of China
174 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...