Ontology type: schema:ScholarlyArticle
2007-08
AUTHORSR. N. Ibbett, S. Kaenthong, D. A. S. Phillips, M. A. Wilding
ABSTRACTThe total water capacity of a series of never-dried and re-wetted cellulosic fibres has been shown to correlate with the accessible volume described by a thermodynamic model. The model was applied to interpret the adsorption behaviour of a range of reactive dyes in electrolyte solutions and was successful in accounting for differences in fibre anionic charge. Comparative solute exclusion data indicated the existence of a population of very small spaces in never-dried cellulosic fibres, which may be associated with water disrupting the cellulose \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${1\overline{1}0}$$\end{document} crystal planes. Such intra-crystalline spaces may provide sites for uptake of planar substantive dyes and may also be accessible to sodium ions. The study showed that never-dried lyocell undergoes a large reduction in total wet capacity following initial drying, which is believed to be due to both exudation of crystal water and to inter-fibrillar crystallisation. This crystallisation mechanism may not be so effective for viscose and modal, which have poorer structural organization. Re-wetted lyocell exhibits high dye adsorption, which may result from the development of a uniform fibrillar morphology with a high surface area. This structural aspect is not expressed by the thermodynamic model. More... »
PAGES6809-6818
http://scigraph.springernature.com/pub.10.1007/s10853-006-1426-4
DOIhttp://dx.doi.org/10.1007/s10853-006-1426-4
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1000096996
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"Christian Doppler Laboratory for Fibre and Textile Chemistry in Cellulosics, School of Materials, University of Manchester, M60 1QD, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Ibbett",
"givenName": "R. N.",
"id": "sg:person.011607476155.52",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011607476155.52"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"Christian Doppler Laboratory for Fibre and Textile Chemistry in Cellulosics, School of Materials, University of Manchester, M60 1QD, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Kaenthong",
"givenName": "S.",
"id": "sg:person.015101351551.54",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015101351551.54"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"Christian Doppler Laboratory for Fibre and Textile Chemistry in Cellulosics, School of Materials, University of Manchester, M60 1QD, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Phillips",
"givenName": "D. A. S.",
"id": "sg:person.013367314627.07",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013367314627.07"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"Christian Doppler Laboratory for Fibre and Textile Chemistry in Cellulosics, School of Materials, University of Manchester, M60 1QD, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Wilding",
"givenName": "M. A.",
"id": "sg:person.016354505675.90",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016354505675.90"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1002/actp.1992.010430603",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005281661"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051756803800703",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006375981"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051756803800703",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006375981"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.10256",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007577373"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/bit.260430506",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009892890"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051756303300106",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012333405"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051756303300106",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012333405"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/1097-4628(20010228)79:9<1726::aid-app220>3.0.co;2-o",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012998484"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1111/j.1478-4408.2005.tb00248.x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018534715"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0143-7208(96)00058-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019827010"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1080/19447024808659403",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021070916"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0079-6700(01)00025-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021416039"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0143-7208(02)00007-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021792339"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/bit.260290809",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026364513"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051750407400608",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029182175"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051750407400608",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029182175"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0021-9673(00)80335-0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1032713209"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0032-3861(99)00502-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035082841"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/apmc.1981.050950102",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037090576"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.dyepig.2005.06.010",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044989055"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.20294",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1046231788"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0377-0273(98)00043-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048438947"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b401055h",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048510155"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.dyepig.2004.01.001",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052665781"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051757204200906",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054030858"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051757204200906",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054030858"
],
"type": "CreativeWork"
}
],
"datePublished": "2007-08",
"datePublishedReg": "2007-08-01",
"description": "The total water capacity of a series of never-dried and re-wetted cellulosic fibres has been shown to correlate with the accessible volume described by a thermodynamic model. The model was applied to interpret the adsorption behaviour of a range of reactive dyes in electrolyte solutions and was successful in accounting for differences in fibre anionic charge. Comparative solute exclusion data indicated the existence of a population of very small spaces in never-dried cellulosic fibres, which may be associated with water disrupting the cellulose \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${1\\overline{1}0}$$\\end{document} crystal planes. Such intra-crystalline spaces may provide sites for uptake of planar substantive dyes and may also be accessible to sodium ions. The study showed that never-dried lyocell undergoes a large reduction in total wet capacity following initial drying, which is believed to be due to both exudation of crystal water and to inter-fibrillar crystallisation. This crystallisation mechanism may not be so effective for viscose and modal, which have poorer structural organization. Re-wetted lyocell exhibits high dye adsorption, which may result from the development of a uniform fibrillar morphology with a high surface area. This structural aspect is not expressed by the thermodynamic model.",
"genre": "research_article",
"id": "sg:pub.10.1007/s10853-006-1426-4",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1312116",
"issn": [
"0022-2461",
"1573-4811"
],
"name": "Journal of Materials Science",
"type": "Periodical"
},
{
"issueNumber": "16",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "42"
}
],
"name": "Solute adsorption and exclusion studies of the structure of never-dried and re-wetted cellulosic fibres",
"pagination": "6809-6818",
"productId": [
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s10853-006-1426-4"
]
},
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"00761793e8a06d3c7029fa19fb1e362c1c6408df9ec00dc53f21e23ebdd03540"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1000096996"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s10853-006-1426-4",
"https://app.dimensions.ai/details/publication/pub.1000096996"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-15T09:18",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000376_0000000376/records_56176_00000000.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007%2Fs10853-006-1426-4"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10853-006-1426-4'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10853-006-1426-4'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10853-006-1426-4'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10853-006-1426-4'
This table displays all metadata directly associated to this object as RDF triples.
148 TRIPLES
21 PREDICATES
49 URIs
19 LITERALS
7 BLANK NODES