Investigation of β-cyclodextrin complex formation with 2,2′-dipyridine in ground and excited triplet states View Full Text


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Article Info

DATE

2017-10

AUTHORS

Simon V. Babenko, Yuri P. Tsentalovich, Alexander I. Kruppa

ABSTRACT

It was found that 2,2′-dipyridine (DP) forms inclusion complex with beta-cyclodextrin (CD) in basic water solution by using NMR and spectrophotometry. Complex formation does not have an effect on the yield of triplet excited 2,2′-dipyridine. Triplet excited 2,2′-dipyridine (3DP) also forms inclusion complex with beta-cyclodextrin and the value of complex formation constant is close to that for DP in the ground state. The electron transfer rate constant between the inclusion complex of 3DP with CD and N-acetyl-l-tyrosine (TyrOH) is about ten times less than between3DP in free (non complexed) state and TyrOHin basic (pH 11) solution. Also it was found that inclusion complex formation of 3DP with CD slightly decreases the rate constant of triplet–triplet annihilation process. More... »

PAGES

117-125

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10847-017-0736-2

DOI

http://dx.doi.org/10.1007/s10847-017-0736-2

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https://app.dimensions.ai/details/publication/pub.1090651392


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