Molecular clips based on diphenylglycoluril and benzocrown ethers: promising complexing agents for the alkali metal cations View Full Text


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Article Info

DATE

2014-08

AUTHORS

Leonid S. Kikot’, Alexander Yu. Lyapunov, Catherine Yu. Kulygina, Tatiana Yu. Bogaschenko, Roman I. Zubatyuk, Oleg V. Shishkin, Tatiana I. Kirichenko

ABSTRACT

The interaction of new molecular clips containing diphenylglycoluril and benzocrown ethers moieties with alkali metals ions was studied. Stability constants were determined by spectrophotometric titrations with chloride salts in methanol. Complex stability and cation binding selectivity were shown to be dependent on the size of the crown ether moiety. The “sandwich-type” 1:1 (clip to cation) complexes and the “classical” 1:2 complexes were found. Their ratio varies depending on the molecular clips nature and on the cation type. It was found an unexpected selectivity of the molecular clip with benzo-15-crown-5 moieties toward K+ and Rb+ cations. The molecular structure of the clip complex with benzo-15-crown-5 fragments and sodium picrate was determined by X-ray crystallography. The crystal structure and solution-state structure were proven to be similar. More... »

PAGES

343-348

References to SciGraph publications

  • 2004-10. Cucurbiturils–a New Family of Host Molecules in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • 2011-07. Americium(III) sorption from multicomponent solutions by macrocyclic polyester-based sorbents in RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • 2009-02. Unexpected 3:2 stoichiometry and structure of 15-crown-5 complex with lithium chlorochromate in STRUCTURAL CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10847-013-0357-3

    DOI

    http://dx.doi.org/10.1007/s10847-013-0357-3

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1027839909


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    263 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
    264 schema:name Department of X-ray Diffraction Studies and Quantum Chemistry, SSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, Lenina Ave. 60, 61001, Kharkiv, Ukraine
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    266 https://www.grid.ac/institutes/grid.493162.b schema:alternateName Physical-Chemical Institute O. Bogatsky
    267 schema:name Department of Fine Organic Synthesis, A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Lustdorfskaya Doroga 86, 65080, Odessa, Ukraine
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