Detection of Zn2+ ion on a reusable fluorescent mesoporous silica beads in aqueous medium View Full Text


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Article Info

DATE

2013-12

AUTHORS

Mohammad Shahid, Priyanka Srivastava, Syed S. Razi, Rashid Ali, Arvind Misra

ABSTRACT

An efficient sensor system was designed and built by immobilizing a fluorescent bischromophoric dyad through a sol–gel reaction on mesoporous silica beads of high surface area. The silica supported dyad, SSD containing anthracene and naphthalimide moieties have shown high sensitivity and selectivity to detect Zn2+ among the tested cations in aqueous medium. The Job’s plot analysis showed a 1:1 stoichiometry for a complexation between SSD and Zn2+ in which the relative fluorescence intensity enhanced, ~6 times due to restricted photoinduced electron transfer reaction and color of the beads were changed from a fluorescent yellow green to blue. The reversible mode of complexation was tested in the presence of EDTA. More... »

PAGES

241-248

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10847-012-0238-1

DOI

http://dx.doi.org/10.1007/s10847-012-0238-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047962838


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44 schema:description An efficient sensor system was designed and built by immobilizing a fluorescent bischromophoric dyad through a sol–gel reaction on mesoporous silica beads of high surface area. The silica supported dyad, SSD containing anthracene and naphthalimide moieties have shown high sensitivity and selectivity to detect Zn2+ among the tested cations in aqueous medium. The Job’s plot analysis showed a 1:1 stoichiometry for a complexation between SSD and Zn2+ in which the relative fluorescence intensity enhanced, ~6 times due to restricted photoinduced electron transfer reaction and color of the beads were changed from a fluorescent yellow green to blue. The reversible mode of complexation was tested in the presence of EDTA.
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