Ontology type: schema:ScholarlyArticle
2013-12
AUTHORSMohammad Shahid, Priyanka Srivastava, Syed S. Razi, Rashid Ali, Arvind Misra
ABSTRACTAn efficient sensor system was designed and built by immobilizing a fluorescent bischromophoric dyad through a sol–gel reaction on mesoporous silica beads of high surface area. The silica supported dyad, SSD containing anthracene and naphthalimide moieties have shown high sensitivity and selectivity to detect Zn2+ among the tested cations in aqueous medium. The Job’s plot analysis showed a 1:1 stoichiometry for a complexation between SSD and Zn2+ in which the relative fluorescence intensity enhanced, ~6 times due to restricted photoinduced electron transfer reaction and color of the beads were changed from a fluorescent yellow green to blue. The reversible mode of complexation was tested in the presence of EDTA. More... »
PAGES241-248
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DOIhttp://dx.doi.org/10.1007/s10847-012-0238-1
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