Synthesis and stereochemical configuration of inherently chiral p-tert-butylcalix[4]arene carboxylic acids and their derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-08-31

AUTHORS

Andrii O. Karpus, Oleksandr A. Yesypenko, Leonid P. Andronov, Vyacheslav I. Boyko, Zoia V. Voitenko, Alexander N. Chernega, Vitaly I. Kalchenko

ABSTRACT

Both enantiomers of inherently chiral p-tert-butylcalix[4]arene carboxylic acids with ABHH substitution patterns have been prepared by stereoselective reaction of monopropoxy-p-tert-butylcalix[4]arene with an (R)-N-(1-phenylethyl)bromoacetamide, separation of the diastereomers by column chromatography, and removal of the chiral auxiliary groups. The absolute configuration of obtained compounds has been established by X-ray analysis.Graphical Abstract

PAGES

175-181

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10847-012-0231-8

DOI

http://dx.doi.org/10.1007/s10847-012-0231-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030056949


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